水相合成发光cds和cdtecds核壳结构量子点-synthesis of luminescent cds and cdte cds core-shell quantum dots in aqueous phase.docxVIP

ABSTRACTResearchonthefieldofsemiconductorquantumdots,quantumwellsandatomicandmolecularclusterhasincreaseddramaticallyinthepasttwodecades.Semiconductornanocrystals,orcolloidalquantumdots,arecurrentlyofgreatinterest,andtheirapplicationsinlight-emittingdevices,cavityquantumelectrodynamicsandbiolabelingdemandanarrowsizedistribution,photostability,designedsurfaceproperties,andhighluminescencequantumyields.Numerousstudiesareknownfocusingonsurfacechemistry,cappingstrategiesandenhancementofphotoluminescenceefficiencies.InparticularforCdSquantumdotsandassociatedwithit,theopticalpropertiesofexcitonconfinedinsuchnanocrystalshavebeenthoroughlyexamined,andtheimportanteffectofexchangeinteractionforground-statesymmetries,finestructure,andPLdynamicshasbeenexplored.UnlikenanocrystalsofCdSe,CdTe/CdScoreshellnanocrystalsaremuchlessstudied.ThispaperstudiestheeffectsofthesynthesisconditionsofCdSandcore-shellCdTe/CdSquantumdotsontheiropticalproperties.Themainresearchcontentsareasfollows:Throughthewater-phasesynthesismethodCdSquantumdotsisprepared.Thesodiumtripolyphosphate(Na5P3O10)isasastabilizingagent,sodiumsulfide(Na2S)andcadmiumnitrate(Cd(NO3)2?4H2O)areassulfurandcadmiumprecursor,respectively.Throughthewater-phasesynthesismethodCdTe/CdScore-shellquantumdotsisprepared.The3-Mercaptopropionicacid(MPA)isasstabilizer.IndifferentexperimentalconditionsincludingdifferentCd2+concentrationandpHwesynthesizedtheCdTe/CdScore/shellquantumdots.Theopticalpropertiesofquantumdotsareobtainedbyultravioletlight,FT-IR,UV-Visspectrophotometerandfluorescencephotometer.Andtheabsorptionandemissionspectraareobtained.IntheexperimentwefoundthattheparticlesizeofCdSquantumdotshasareductionintheconcentrationofNa2S,andtheamountofCdSquantumdotshaveincreasedwiththereactiontime,buttheparticlesizedonotchange.WehaverespectivelysynthesizedthedifferentsizeCdSandCdTe/CdScore/shellquantumdotsindifferentexperimentalconditionsandanalyzedtheiremissionandabsorptionspectra.ItsabsorptionandemissionspectrainpH=8.5reachthemaximum,and