水性聚氨酯分子结构与粘结强度的关系研究-study on the relationship between molecular structure and bonding strength of waterborne polyurethane.docxVIP

ResearchontherelationshipbetweenWaterbornepolyurethanemolecularstructureandtheadhesivestrengthAbstractAsakindnewpolymermaterial，polyurethane（PU）iswidelyused．Organicsolventsusedinsolvent-basedpolyurethaneisharmfultoenvironment．Inordertoreduceenvironmentalpollutionofsolventevaporation,moreandmoreattentionisfocusedonresearchanddevelopmentofwater-basedpolyurethaneworldwide.Therelationshipbetweenwaterbornepolyurethanemolecularstructureandtheadhesivestrengthisinvestigatedinthispaper,andthemaincontentsareasfollows:EffectbetweenadhesivestrengthwithHMDI-basedwaterbornepolyurethaneAseriesofwaterbornepolyurethaneadhesivesarepreparedinthepre-polymerprocesswithpoly(tetramethy-leneoxideglycol)(PTMEG)，4,4-dicyclohex-ylmethanediisocyanate(HMDI)，2,2-Dimethylolpro-pionicacid(DMPA)，1,4-butanediol(BDO)．ThepropertiesofWPUarecharacterizedbywaterabsorption，ethanolswelling，tensilestrengthtestingandadhesivestrength．EffectofwaterbornepolyurethaneadhesiveonHMDIcontent，DMPAcontent，PTMEGmolecularweight，thesizeofRvaluesarealsoinvestigated．Theresultsshowthatthemaximumvalueoftensilestrengthandadhesivestrengthare11.48Mpaand0.56Mpa,whenthecontentofHMDIis33wt%，chainextenderis5wt.%，valueofRis1.2，andthesoftsegentsmolecularweightofpolyetherpolyolsis2000．EffectbetweenadhesivestrengthofwaterbornepolyurethanemodifiedwithsilanecouplingagentKH-602Inordertoimprovetheadhesivestrengthofwaterbornepolyurethane，HMDI-basedwaterbornepolyurethaneismodifiedwithsilanecouplingagent(KH-602)．SilanecouplingagentcandeclinesurfacetensionandtheWPUeasilywettingsubstratebetter，theadhesivestrengthhadbeenimprovedalot．Silanecouplingagentcanincreaseadhesivebythewayoftheformationofmeshstructure，allofthesemadethematerialwithgoodsolventresistance(ethanol)，andmechanicalpropertiesandadhesivestrengthhadbeenimprovedconsiderably．Theresultshowed:silanecouplingagentis2wt.%，theadhesivestrengthofmodifiedWPUcanreachupto0.71Mpa，muchhigherthantheunmodifiedWPU(adhesivestrengthisonlyof0.56Mpa).UnmodifiedWPUdissolvedinethanolcompletely,whileethanolr