石墨烯和氧化石墨烯的制备及力学性能分析-preparation and mechanical properties analysis of graphene and graphene oxide.docxVIP

AbstractInthispaper,graphenematerialswerepreparedbychemicalmethod,andstudiesonitsapplicationwerecarriedout.Flexiblehybirdgraphene/TiO2filmhasbeenfabricatedbyasimplesolventevaporationtechnique.Themorphology,structureandelectrochemicalperformanceofthehybirdfilmwerecharacterizedbyscanningelectronmicroscopy(SEM),atomicforcemicroscopy(AFM),X-raydiffraction(XRD),andbattery-testequipment.Ultra-lightporousnanostructuregrapheneoxide(GO)foamswerepreparedbyvacuumfreezedryingtechnique.MechanicalpropertiesofGOfoamswithdifferentdensitywereinvestigatedunderuniaxialcompressionatdifferentstrainrates.EffectsofdensityandstrainratesonmechanicalperformanceofGOfoamswerealsodiscussed.GOfoamexhibitedexcellentelasticity,whichrecoveredtoitsoriginalheightevenafter300cycles.Furthermore,themechanicalperformanceofGOfoamexhibitedagoodhumiditysensitivity.TheelasticmodulusofporousGOstructurewasderivedbasedonGibsonhoneycombmodel.Finallytheeffectsofstructuralparametersonelasticmoduluswerestudied.Keywords:graphene;grapheneoxide(GO);porousstructure;hybridfilms;Gibsonmodel目录第1章绪论.............................................................................................................11.1引言................................................................................................................1Graphene的由来1Graphene和GO的结构2Graphene的性质31.4.1电学性能..................................................................................................31.4.2力学性能..................................................................................................41.4.3光学性能..................................................................................................41.4.4热导性能..................................................................................................5Graphene的制备61.5.1机械剥离法..............................................................................................61.5.2化学气相沉积法......................................................................................71.5.3化学氧化还原法...............