4-氨基安替比林希夫碱的合成、晶体结构和其荧光性质研究.pdf

Journal of Organic Chemistry Research 有机化学研究, 2017, 5(1), 1-7 Published Online March 2017 in Hans. /journal/jocr /10.12677/jocr.2017.51001 Study on Synthesis, Crystal Structure and Fluorescence Properties of Schiff Base from 4-Aminoantipyrine Qiaoru Liu, Yaxin Zhao, Qinlong Peng, Lingwei Xue, Ganqing Zhao College of Chemistry and Environmental Engineering, Pingdingshan University, Pingdingshan Henan th th th Received: Feb. 25 , 2017; accepted: Mar. 5 , 2017; published: Mar. 8 , 2017 Abstract The title compound Schiff base was synthesized from salicylaldehyde and 4-aminoantipyrine. Its structure was characterized by IR, 1H NMR, Elemental Analyzer and X-ray single-crystal diffraction. Fluorescent property about the title compound complexed with five kinds of metal ions was inves- tigated. The results show that the compound crystallizes in the monoclinic space group P2(1)/n with cell parameters: a = 0.7603 nm, b = 0.7508 nm, c = 2.7246 nm, α= 90.00˚, β= 95.43˚, γ= 90.00˚. 3 3 −1 −3 V = 1.548 nm , Z = 4, Dc = 1.314 g/cm , μ= 0.088 mm , F (000) = 648, ρ = 218 e∙nm , ρ = −155 max min e∙nm−3. The complexes exhibited strong fluorescence absorption at 676 nm (λ ). Fluorescence max enhancement effect produced by Cu2+, Co2+ is remarkable. Keywords Schiff Base, 4-Aminoantipyrine, Crystal Structure, Fluorescence Property 4-氨基安替比林希夫碱的合成、 晶体结构及其荧光性质研究 刘巧茹，赵亚新，彭勤龙，薛灵伟，赵干卿 平顶山学院化学与环境工程学院，河南 平顶山 收稿日期：2017年2月25 日；录