石墨烯基半导体纳米复合材料的制备及其在光催化还原co2中的应用-preparation of graphene-based semiconductor nanocomposites and their application in photocatalytic reduction of co2.docxVIP

的产量是单纯的ZnO的5倍；ZnO-rGO纳米复合材料具有良好的重复使用性能。（3）采用一步溶剂热法，以乙二醇为溶剂，硫代乙酰胺（TAA）为硫源，制备出了还原氧化石墨烯（rGO）-Bi2S3纳米棒复合材料。采用X射线衍射（XRD）、透射电镜（TEM）、傅里叶红外光谱（FTIR）和紫外可见漫反射光谱（DRS）对制备的样品进行了表征，并在可见光照下考察其还原二氧化碳的活性。结果表明：直径为20~30nm、长度为100~200nm的Bi2S3纳米棒随意的排列在rGO表面上。复合催化剂较单纯的Bi2S3纳米棒具有较高的光还原能力。关键词：石墨烯，半导体，复合光催化剂，还原，二氧化碳PreparationofGrapheneBasedSemiconductorNanocompositesforPhotocatalyticReductionofCO2AbstractThephotocatalyticconversionofCO2intorenewablehydrocarbonfuelsisbelievedtobeoneofthebestmethodstoovercomeboththeenergycrisisandenvironmentalproblems.Todesignanefficientphotocatalystisakeyfactorinimprovingthephotocatalyticactivity.Graphenecanbeusedasanidealsupportertoimprovethephotoelectricpropertyofsemiconductornanomaterials,duetoitsuniqueelectronictransmissioncapacity.Graphene-basedsemiconductormaterialshasbecomethefocusoftheworldattentionforitsphotocatalyticapplication.Inthiswork,wetrytoprepareaseriesofgraphene-basedsemiconductorphotocatalysts,andresearchtheirphotocatalyticactivitiesofreductionCO2.Themaincontentsaregivenasfollows:Reducedgrapheneoxide(rGO)-TiO2nanotubecompositesweresynthesizedbyasimpleone-pothydrothermalmethodusinggraphiteoxideandtitaniumdioxideasrawmaterialsandgraphiteoxidewaspreparedbymodifiedHummersmethod.ThesampleswerecharacterizedbyX-raydiffraction(XRD),Transmissionscanningelectronmicroscopy(TEM),Fouriertransforminfraredspectra(FTIR),andUV-visdiffusereflectance(DRS).ThephotocatalyticperformancewereresearchedforthereductionofCO2undersimulatedsunlightirradiation.Characterizationresultsindicatethat:TiO2nanotubesareuniformlyloadedonthesurfaceofrGOnanosheets;TheintroductionofrGOwidensTiO2nanotuberesponserangetowardslight.Experimentalresultsshowthat:ThephotocatalyticactivityofcatalystinthereductionofCO2isobviousenhancedafterincorporatingappropriaterGOandTiO2nanotube;Undertheconditionsofgrapheneoxidemassfraction5%andphotocatalystdosage1.5g/L,theactivityofrGO-TiO2nanotubecompositeisfourtimesashigherasthatofTiO2nanotube;TherGO-TiO2nanotubecompositespossessexcellentcyclingpropert