石墨烯及其聚合物复合薄膜的制备与性能分析-preparation and performance analysis of graphene and its polymer composite films.docxVIP

AbstractGrapheneis2Dcarbonnanomaterialwithsp2carbonatoms.Studiesshowthatithasmanyexcellentproperties,suchashightheoreticalspecificsurfacearea,highchargemobility,excellentmechanicalproperties.Theseexcellentpropertiesmakegraphenehavehugepotentialapplications.inbio-medicine,supercapacitors,solarcells,adsorption,corrosionandmanyotherfields.Inthispaper，graphiteoxidewasfabricatedbyHummersoxidationwithnaturalgraphiteasrawmaterial，thenbemodifiedandrestoredtopreparefunctionalizedgraphene.ThestructuresoftheproductswerecharacterizedbyXRD,FT-IR,SEMandsoon.Onthisbasis,OursamplesweredevelopedfortheremovalofCu(II)ionsfromwater.TheresultsshowedthatthemaximumadsorptioncapacityofCu(II)ionsisupto1689mg/g，whichismuchhigherthanthatbyprevioussample.nanotube．Theadsorptionprocessesreachequilibriuminjusttenminutes.TheseillustratethatoursampleshaveexcellentadsorptioncapacityandpotentialindustrialapplicationsprospectsforCu(II)ions.Compositefilmswithdifferentcontentofgraphenewerepreparedbyaddinggraphenetotheepoxyresin.ThestructureandpropertiesoftheproductswerecharacterizedbyRaman,SEM,TG,nanoindentation,electrochemicaltesting.Theresultsshowedthatthemodulusofdoping0.7wt%grapheneishighestfor5.62GPa,increasedbyabout213%comparedwiththatofthepureepoxy(2.44GPa).Thecorrosioncurrentofdoping0.7wt%grapheneislowestfor0.18μA/cm2,reducedbyaboutfourtimescomparedwiththatofthepureepoxy（0.75μA/cm2），correspondingcorrosionrateis0.3mm/year,lessthanthatofpureepoxy(1.3mm/year).Compositefilmswithdifferentcontentofgraphenewerepreparedbyaddinggraphenetotheacrylicemulsion.ThestructureandpropertiesoftheproductswerecharacterizedbyRaman,SEM,TG,bubbling,electrochemicaltesting.Theresultsshowedthattheyieldstressofdoping1.1wt%grapheneishighestfor24.1GPa,increasedbyaboutthreetimescomparedwiththatofpureacrylicemulsion(8.2GPa).Thecorrosioncurrentofdoping1.1wt%grapheneislowestfor0.45μA/cm2,reducedbyaboutthreeordersofmagnitudecomparedwiththatofpureacrylicemulsion（13.8μA/cm2），correspondingcorrosionrateis0.8mm/year,lessthanthatofpure