石墨-ptfe阴极制备及电芬顿反应处理染料废水-preparation of graphite - ptfe cathode and treatment of dye wastewater by electro - fenton reaction.docxVIP

AbstractInrecentyears,varioustreatmentprocesseshavebeeninvestigatedtoavoidthedangerousaccumulationofthetoxicdyesintheenvironment.Amongofthem,indirectelectro-oxidationmethodswithelectro-generatedhydrogenperoxide,suchaselectro-Fenton(EF)andphotoelectro-Fenton(PEF)processes,havebeendevelopedforthetreatmentoftoxicandrefractoryorganicpollutantsinacidicwater.Thedegradationofacidfuchsine,methylorangeand2,4-dichlorophenolbyelectro-Fentontechniquewasstudiedinthispaper.Thecurrentmodifiedelectro-Fentonsystemwasdesignedtodevelopamoreconvenientandefficientundividedsystemforpracticalwastewatertreatment.Thesystemadoptedacathodeportion,whichemployedmagneticstirringinsteadofcommonoxygengasdiffusionorgasspargingtosupplyoxygengasfortheelectrolytesolution.Thegraphite-polytetrafluorethylenecathodewaspreparedandkeyfactorsinfluencingthecathodefabricationandactivitywereinvestigated.Itwasfoundthatthecathodegeneratedhydrogenperoxidewithhighercurrentefficiencywhenoxygengaswassuppliedonlybythemagneticstirring,andcalcinationtemperatureinfluencedtheperformanceofthegraphite-polytetrafluorethylenecathoderemarkably.Hydrogenperoxideyieldwasthehighestwhenthecathodewitharatioofgraphite:polytetrafluorethyleneof4:1(m/m)orof3:1(m/m)wascalcinatedat350℃for1h.Whenthecurrentdensitywas3mA/cm2,pHwas3,thevolumeofelectrolytewas200mL,andoxygengaswassuppliedbythemagneticstirring,theconcentrationofH2O2electrochemicallygeneratedbythegraphite-polytetrafluorethylenecathode(12cm2)wasabletobe114mg/Lafter150min.Thehydrogenperoxideyieldofthecathodedidnotdecayafter10timesreuse.Theseresultssuggestthepreparedcathodehaveagoodstabilityanditcanbeusedforpracticalwastewatertreatment.Atthesametime,thedegradationofacidfuchsinebytheelectro-FentonIIsystemswitheitheraFeanodeoraPtanodewithexternalferrousionandagraphite-polytetrafluorethylenecathodewerestudiedusingaspectrophotometer.WhenPtwasusedasanodeandexternalferrousionwas0.5mmol/L,thedyedecolorizationcouldberapidlyaccomplishedbutthedestructionofbenzeneringsandintermediateswasdiffic