鱼鳞结构化g-C3N4 nanosheet以不同寻常的空间电子转移财产高效光催化氢进化：（Fish-scale structured g-C3N4 nanosheet with unusual spatial electron transfer property for high-efficiency photocatalytic hydrogen evolution）.pdfVIP

Applied Catalysis B: Environmental 210 (2017) 173–183 Contents lists available at ScienceDirect Applied Catalysis B: Environmental j o u r na l h o m e p ag e: w w w. elsev /locate/apc atb Fish-scale structured g-C3 N4 nanosheet with unusual spatial electron transfer property for high-efficiency photocatalytic hydrogen evolution Bo Lin, Hua An, Xiaoqing Yan, Tianxi Zhang, Jinjia Wei, Guidong Yang ∗ Department of Chemical Engineering, School of Chemical Engineering and Technology, Xi’an Jiaotong University, Xi’an 710049, China a r t i c l e i n f o a b s t r a c t Article history: Grafing the structures in nature onto g-C3 N4 is an interesting and fascinating protocol to highly optimize Received 25 January 2017 its performances. Herein, a novel opened-up fish-scale structured g-C3 N4 nanosheet has been synthesized Received in revised form 15 March 2017 via a simple one-step solvothermal method for photocatalytic hydrogen evolution. The unique fish-scale Accepted 25 March 2017 structure endows g-C3 N4 with unusual spatial electron transfer property, which means that the pho- Available online 27 March 2017 togenerated electrons selectively migrate along the flat direction to the edges of fish-scale flakes. This property well reveals the transfer path of photogenerated charges and the origin of high charge separation Keywords: efficiency in photocatalytic reaction, thus yielding a remarkable catalytic activit