碱性离子液体有效去除烟梗中木质素研究.docVIP

碱性离子液体有效去除烟梗中木质素的研究 　　摘 要：制备碱性离子液体[Mmim]DMP，将其作为溶剂，以微波辐射为加热源，研究其对造纸法再造烟叶原料烟梗中木质素的去除效果.建立了快速、准确的液相木质素紫外分光光度定量分析方法，通过正交实验确定了碱性离子液体有效去除烟梗中木质素的最佳工艺：浸渍温度80 ℃，浸渍时间25 min，浸渍料液比1∶15.在此工艺条件下，烟梗木质素的去除率达到22.60%，其溶解去除率约为常规热水提取的5倍.烟梗经离子液体处理后，纤维间的填充物大量脱除，纤维轮廓更清晰，有利于后续原料打浆及烟气品质控制. 　　关键词：烟梗；碱性离子液体；液相木质素；有效去除 　　中图分类号：TS424 文献标志码：A 　　Study on Effective Removal of Lignin in Tobacco Stems byUsing Alkaline Ionic Liquids 　　HOU Yi1，2，HU Yacheng1，LI Youming1，LIU Chao1，YANG Yufei1，HU Songqing1 　　（1.State Key Laboratory of Pulp and Paper Engineering，South China University of Technology， 　　Guangzhou 510640，China； 2. China Tobacco Chongqing Industrial Co Ltd，Chongqing 400060，China） 　　Abstract：Making alkaline ionic liquid [Mmim] DMP and using it as solvent by microwave heating，the effective removal of lignin in tobacco stems of reconstituted tobacco was studied. A rapid and accurate method for quantitative determination of liquid lignin by using UV spectrometry was established. The optimum technology for the removal of lignin in tobacco stems with the ionic liquids was determined by orthogonal experiment as follows： a maceration temperature of 80℃，a maceration time of 25 min and a solid /liquid ratio of 1∶15. In this process，the removal rate of lignin was 22.60%. The removal rate was about 5 times of that of water extraction. After extraction of tobacco stems by using ionic liquids，the fillers of fiber were removed heavily and the fiber profile was clearer，which were conducive to the pulping of the subsequent raw materials and the control of smoke quality. 　　Key words：tobacco stems； alkaline ionic liquids； liquid lignin； effective removal 　　再造??叶最初是提高对烟草废弃物的利用，现已发展成为改善烟草化学品质和味觉品质的一种途径.其中造纸法再造烟叶工艺已成为再造烟叶技术的主流，其制造工艺是将烟叶加工过程中废弃的烟梗、烟末等原料，经过浸取、浓缩、打浆、抄造、涂布等过程，制备出品质接近于天然烟叶的产品，将其回用到卷烟生产中，可降低生产成本，实现卷烟的化学成分的可控性[1-3].大多数研究人员和生产商更多地关注再造烟叶原料中烟草特征香味物质的浸提和涂布[4-6]，而忽视了原料主要成分――木质素对烟气及造纸法再造烟叶工艺过程带来的不利影响.烟草废弃物尤其是烟梗作为再造烟叶浆料纤维的主要来源，其木质素含量较高，由于木质素热解时产生儿茶酚和烷基儿茶酚，抽吸时引起涩口且有促癌活性 [7-9]，故烟梗在卷烟产品中的用量受到了很大的限制.