稀土对铝合金硫酸—草酸阳极氧化的影响-effect of rare earth on anodic oxidation of aluminum alloy with sulfuric acid and oxalic acid.docx

下载文档 降价啦

10
0
约6.02万字
约 83页
2018-08-07 发布于上海
举报
版权申诉
保障服务

稀土对铝合金硫酸—草酸阳极氧化的影响-effect of rare earth on anodic oxidation of aluminum alloy with sulfuric acid and oxalic acid.docx

1、本文档共83页，可阅读全部内容。
2、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。
3、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
4、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。

稀土对铝合金硫酸—草酸阳极氧化的影响-effect of rare earth on anodic oxidation of aluminum alloy with sulfuric acid and oxalic acid

TheInfluenceofrareearthonanodicoxidationofaluminumalloyinSulfuricAcid-oxalicAcidAbstractThisarticlestudiedthebasicmechanismofsulfuricacid-oxalicacidanodicoxidationwhichconfirmedtheoptimumcraftandformulainsulfuricacid-oxalicacidanodicoxidationandanalyzedtheeffectofrareearthoncorrosionresistance,surfacemorphologyandelectrochemicalpropertyofanodizingfilms.Theoptimumprocessparameterswasdeterminedbyorthogonalexperimentsandthevariousaffectingfactorswereasfollows:sulfuricacid180g/L，oxalicacid5g/L，glycerol15g/L，oxidationtemperature20℃，oxidationvoltage16V，oxidationtime50min.AconclusionhadbeendrawnthattheanodizingfilmsmainlyconsistedofamorphousAl2O3whichwascomposedoftwoelementsAlandObyobservingthesurfacemorphologyoftheanodizingfilmsbyscanningelectronmicroscopy(SEM)andevaluatingthedeterminationofthechemicalcompositionoftheanodizingfilmsbyenergydispersivespectroscopy(EDS)andthestructureoftheanodizingfilmsbyX-raydiffraction(XRD)theanodizingfilms.TheoptimaldosageofCeandLawas0.2g/L,whichwasfoundthroughimmersioncorrosiontestsofthefivesolution(acid,alkali,neutralsalt,acidsaltandalkalisalt),XPSanalysisofcorrosionproducts,theneutralsaltspraytest(NSS)andelectrochemicalcorrosiontests.Thecorrosionresistanceofanodizingfilmsintheimmersioncorrosiontestsfollowedtheorderbelow:neutralsaltalkalisaltalkaliacidacidsalt.ThebasiccorrosionproductsofthefivesolutionswereallAl2O3andAl(OH)3.BoththechemicaldissolutionofH+andthepittingofCl-wereexistingatthesametimeintheacidsaltsolution.Thetwoformsofcorrosionacceleratedthecorrosionrateofanodizingfilms.AndanalyzedcorrosionproductsbyX-rayphotoelectronspectroscopy(XPS),itwasfoundthatthecompoundofCl-existedintheanodizingfilms.ButthecompoundofCl-inthealkalisaltsolutionwasnotfoundintheanodizingfilmswhichshowedCl-wasnotinvolvedinthecorrosionprocess.Furthermore,afterboiled,theporouslayerandtheporouswallofaluminaintheanodizingfilmswasreactedtogenerateAl2O3?H2O,soastofilltheholes.Thecorrosionresistancesignificantlyimproveedandthecorrosionratereduced.Intheelectrochem