污泥碱性厌氧发酵产酸的条件优化分析-optimization and analysis of acid production conditions for alkaline anaerobic fermentation of sludge.docxVIP

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污泥碱性厌氧发酵产酸的条件优化分析-optimization and analysis of acid production conditions for alkaline anaerobic fermentation of sludge.docx

污泥碱性厌氧发酵产酸的条件优化分析-optimization and analysis of acid production conditions for alkaline anaerobic fermentation of sludge

AbstractWiththeincreasingamountofsewageslugeproducedbyinlargedwastewaterquantity,sludgetreatmentaswellasdisposalhasbecomeanurgentproblem.MeanwhilenitrogenandphosphorusremovalefficiencyinlowC/Nsewagetreatmentplantsisrestrictedduetolackofcarbonsource.Anaerobicfermentationprocesscaneffectivelytransferparticulateorganicsinexcesssludgetoeasilydegradableorganics,suchasvolatilefattyacids,whoseadditioncangreatlyimprovethesewagenitrogenandphosphorusremovalefficiency.Inthisstudy,theperformanceofanaerobicalkalinefermentationforacidproductionfromactivatedexcesssludgewasinvestigated.Astaticfermentationexperimentwascarriedouttostudytheinfluenceofdifferentalkalitypesonsludgehydrolysisandaddificationperformance,andtheinfluenceoftemperatureandsludgeretentiontimeweresubsequentlyinvestigatedbyrunningfourcontinuous-flowstirredtankreactors.Finally,theoptimumprocessconditionsofthesludgeanaerobicalkalinefermentationwereputforward.Firstofall,bythestaticsludgefermentationexperiment,theinfluenceofdifferentpHsandalkalisonsolubleproductionswerestudied,theresultsshowthat,thealkalineconditionsarebenifittothesludgehydrolysisandacidificationprocess,theconcentrationofdissolvedproductionshasreachedthemaximumatpH10.0.AtthesamepH,NaOHisobviouslymoreconducivetosludgehydrolysisprocess,whiletheeffectofthetwobasesarealmostthesameforvolatilefattyacidproduction.Therefore,pH10.0andtheadditionofCa(OH)2weretakenasoptimumoperatingconditionsforcontinuousflowexperiments.Then,theexperimentusingCSTRwascarriedouttostudytheinfluenceofdifferenttemperaturesontheperformanceofsludgefermentationandacidification.ResultsfoundthatunderSRT8dandpH10.0adjustedbyCa(OH)2,hightemperatureisbenefittosludgehydrolysisandorganicacidification,andtheproductionofprotein,carbohydrateandSCODgraduallyincreasewithtemperatureupgradefrom15℃to55℃,whilevolatilefattyacidsproductionincreasesfirstlyandthendecreaseswithtemperatureover35℃.ThedissolvedconcentrationofhydrolysisproductsreachthehighestSCODconcentrationof4193.8mg/Lattemperature55℃,whilevol

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