推拉型分子双光子吸收的理论分析-theoretical analysis of push-pull molecular two-photon absorption.docxVIP

?十学位论又 中文?留在 始体的供屯子能力也强!溶剂对分子的双光子吸收的影响越大 a 整篇论文共分五章。第一章主要介绍丁非线性光学和观光子吸收材料的研究现状。 第二章介绍丁分早的 3 续性先坐性质为了理解分子的非线性光学传质我们脸在第二军 介绍了合叫做扰理论 E 当分子被窑解在港弃中叶 洛?刊将影响分子的几何结构翔先逆性 质第三章我们介绍浴剂效应.第四章我们介绍了在从头计算禁础 k 的密度泛函到论 n 算过程相结果将在第丑意给:f .. 关键i再 单光子吸收双光子吸收:密定在墨浴到效，C:V 分韭号归37 2 协， 协， 主1古论 J之 英支擒 1民 PAGE PAGE 3 The Studies on the Two Photon Absorption 01 Push-Pu l1 方 Conjugated {、 olecuJe览 (Abstract) Materials 飞NíTh strong !1.().pholOn absorption 仔?创 art: CUlTenlly aUN.:?n毕: ?um4derabk anention in the chemis町 phQtonics and bio]ogy COlllluunities becau 、曰 of their p创etllial applicatiom 】 n optical po 矶 er limitiug， 吗俨con\erted laseri川怠 lhree-dime 1.剖onal dalastorage ，n创立Ldestr.ICtivei!l略ing and photodynam?c Iherapy . Ho，，ver ，the de;.elr 阳ω1 of two-phoron technology isωnfin e.d be 相se of 让Je small TPA cro驾驶ω (1m of illateriais Rece:l.tly，with the de、哈)opment of e.飞p nm:Its， nuπU{\IL ?rgaruc materia山叶lat exhlbll 比气τ^ ，宫。ss sections have been synthe海 ized in differenl laoorato泪e5. Theτ5l也s ，，1 e:penmellts shúw that the most e伍cient TPA mat，臼ia\s 5eenl 10 be the ones with vanous ekwon-do?or (D) and electr。但也ceptor (A) moieties attached S}mmetrically Or ，vmmetri ca[ly 10 a ;，ccnter， ìn order 10 lmderstand the 区ructure-proper飞y rela\ìo!lship ()f matcrial8 with large TPA cross sections and examir.e the TPA properti.es of these mole兀uJ es，a large number of theotetical models 叙e devel句ed to calculate TPA 曰{lS:; sections ofmolecnl e:， . Theoretical calculatiollS can nωonly predicl 也.e two-phul()1l abSOI严ion mt巳nsily bnl also pro\ide g ide)ine and help for synthesis of new materials with 1m-即 TPA croS5 seclions. We have ?1cuhted ono. and two-photon absOrpti011 TOgS soc1以ms of the lowest c，cite:i stl:S of a eηes of molec叫es combined w刊:h ben啤m，飞 stilben 归呻hene aS1r ?en1er att肌h d \.ith amine ，di归仙mine，diethylamine as elutτon -d。即o.nd nicryl 岱 elecrron-acceptor: lhe effcctJ f molecular length.， J! center