铁碳微电解法处理季铵盐生产废水的分析-analysis on treatment of quaternary ammonium salt production wastewater by iron-carbon microelectrolysis.docxVIP

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铁碳微电解法处理季铵盐生产废水的分析-analysis on treatment of quaternary ammonium salt production wastewater by iron-carbon microelectrolysis.docx

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铁碳微电解法处理季铵盐生产废水的分析-analysis on treatment of quaternary ammonium salt production wastewater by iron-carbon microelectrolysis

万方数据万方数据较低（510.82 元/t 废水），具有一定的优越性。（3）通过 GC-MS 分析废水降解不同阶段的出水，得出微电解法处理季铵盐生产废水的降解机理：废水中最主要的有机污染物四丙基氢氧化铵被·OH 攻击，导致支链烷烃的脱落，形成三丙胺。三丙胺进一步被降解成二丙胺；最后，部分二丙胺降解成二乙胺。酯类和胺类化合物等一系列化学键的断裂与重组、电子转移等化学过程的数量减少，生成了醇类、烷烃类等有机物，最后剩余了有较强稳定结构的酸类、胺类有机物。本课题运用微电解法对季铵盐生产废水进行降解，为该废水的处理提供了一种有效的新方法；同时对工程应用进行优化，提高了经济可行性。此处理工艺具有无需对废水稀释、成本低、无需对废水热交换、无需添加电解质等特点，处理效果好，废水停留时间短，工艺流程简单，有“以废治废”的意义，具有其它降解方法无法比拟的优点。关键词：微电解，GC-MS，季铵盐 Study on iron-carbon micro-electrolysis for treatment of the quaternary ammonium production wastewater Abstract Quaternary ammonium compounds production wastewater contains a lot of biodegradation of organic compounds and belongs to difficult biodegradation of high salinity organic wastewater with high COD (1500-2500mg/L) , high pH (9-10) , high concentration of suspended solids, etc. Micro-electrolysis technology combines a number of functions, such as electrochemistry, oxide deoxidation, physical adsorption and flocculation action,and the gain in the electrode surface reaction,produce strong oxidation active substances and treatment of high concentration toxic refractory wastewater. This method has the advantages of high processing efficiency and easy operation, no produce toxic substances,no adding chemical reagents, is environmentally friendly technology. Using micro-electrolysis, study the degradation of QACs production wastewater. Main research contents as: (1)According to the characteristics of high concentrations of COD, the pretreatment method of wastewater was studied and the condition was optimized. (2) To improve the economic viability, comparative study of iron, carbon materials and combinations, while optimizing the reaction parameters and progression. (3)The degradation mechanism and cost analysis of micro-electrolysis QACs wastewater degradation process are be researched. By using GC-MS analysis method to study and analysis on the above experimental results, get the following conclusion: The processing scheme of QACs production wastewater is the three