脱除烧结烟气中氮氧化物的催化剂担载分析-analysis of catalyst loading for removing nitrogen oxides from sintering flue gas.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract NO in flue gas treatment technologies currently is Selective Catalytic Reduction （SCR）, the reductant is NH3.Based on the conclusion which has been listing out in the subject （Study on removal of nitrogen oxides in flue gas Sintering,Yin Lan）, this study is about the preparation of the catalyst for industrytrial. Because of the high pressure drop when the gas goes through the catalytic converter in the industrial test, turbulence caused by the pressure fluctuation, the catalyst volume contraction during the operation ,or the other mechanical factors, and the serious broken caused by collision between the catalyst particle, we take the honeycomb cordierite carrier instead of TiO2 in the experiment. However the active ingredient NaV6O15 in the conclusions will not change. The specific surface area of the honeycomb ceramic carrier is small, so when it is coated of aluminum by 5 percent to 15 percent, the pHysical and chemistical effect of the active ingredient is better than which is uncoating.Pretreatment can enhance the carriers performance.Comparing the experimental result,we found that the carrier, which is boiling in the 20 percent of the oxalate for 2 hours ,is best for the following trial. Taking Al （NO3）3 ? 9 H2O （A.R）and urea as materials, with their Moore ratio is 1: 12, and when the mass ratio of solute and solvent quality is about the 25 percent to 30 percent, we prepared the Al colloid. Under these conditions the honeycomb carrier channels can be filling easily, and the materials serve their proper purpos.The temperature of the preparation requests about 90 ℃ to 100 ℃,and we must turn off the heater 3 min later when the Al colloid forms. After the experiment we can conclude that the best way we prepared for the honeycomb carrier is putting it in the colloid 15 minutes , drying it between 100-120 ℃ for six hours, repeating the process five times and then burned in the 480-520 ℃ for 2.5 hours . The loading