稳定性二氧化氯脱氮除硫技术分析-analysis of nitrogen and sulfur removal technology for stable chlorine dioxide.docxVIP

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稳定性二氧化氯脱氮除硫技术分析-analysis of nitrogen and sulfur removal technology for stable chlorine dioxide.docx

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稳定性二氧化氯脱氮除硫技术分析-analysis of nitrogen and sulfur removal technology for stable chlorine dioxide

中北大学学位论文中北大学学位论文 Study on Removal of NOX and SO2 by Stabilized Chlorine Dioxide ABSTRACT In order to develop new technology of removal of nitrogen oxides (NO X) and sulfur dioxide (SO2), the stability of chlorine dioxide was used as the oxidative absorption liquid in the gas-liquid countercurrent packed column, and N- （ 1-naphthy1) ethylene diamine dihydrochloride spectrophotometric method and ambient air-Tetrachloromercurate (TCM)-pararosaniline method as removal of NOX and SO2 experimental analysis method, respectively. A comprehensive test of the packing height, chlorine dioxide concentration, pH value, the concentration of NOX and SO2, liquid-gas ratio and other operating factors were studied to impact on the removal rate of the NOX and SO2. The experimental results showed that: Orthogonal experiments were used on the study of removal of nitrogen oxides by stabilized chlorine dioxide. Experimental results showed that:the NOX removal efficiency was of 90% when media height of 30cm, chlorine dioxide concentration of 0.6g/L, pH value of 3.47, NOX concentration of 0.188g/L. It was the best solution. And the results of single factor experiment according to the design showed that the chlorine dioxide concentration was the most significant factor on nitrogen removal rate, the removal of nitrogen oxides decreased from 94.05% to 87.66% when the concentration of chlorine dioxide from 1.0g/L decreased to 0.2g/L, and the NOX concentration was secondary factors of affecting the removal efficiency. Orthogonal experiments were used on the study of removal of sulfur dioxide by stabilized chlorine dioxide. Experimental results showed that:the SO2 removal efficiency was of 99.95% when media height of 30cm, chlorine dioxide concentration of 0.6g/L, pH value of 3.47, the liquid gas ratio of 46.67. And the results of single factor experiment according to the design showed that the concentration of chlorine dioxide from 1.0g/L decreased to 0.2g/L, SO2 removal rate decre