稀土掺杂znxca1-xwo4多晶的制备及上转换发光性能分析-preparation of rare earth doped zn xca1 - xwo 4 polycrystals and analysis of upconversion luminescence properties.docxVIP

下载本文档

3
0
约5.51万字
约 63页
2018-08-10 发布于上海
举报
版权申诉

稀土掺杂znxca1-xwo4多晶的制备及上转换发光性能分析-preparation of rare earth doped zn xca1 - xwo 4 polycrystals and analysis of upconversion luminescence properties.docx

1、原创力文档（book118）网站文档一经付费（服务费），不意味着购买了该文档的版权，仅供个人/单位学习、研究之用，不得用于商业用途，未经授权，严禁复制、发行、汇编、翻译或者网络传播等，侵权必究。。
2、本站所有内容均由合作方或网友上传，本站不对文档的完整性、权威性及其观点立场正确性做任何保证或承诺！文档内容仅供研究参考，付费前请自行鉴别。如您付费，意味着您自己接受本站规则且自行承担风险，本站不退款、不进行额外附加服务；查看《如何避免下载的几个坑》。如果您已付费下载过本站文档，您可以点击这里二次下载。
3、如文档侵犯商业秘密、侵犯著作权、侵犯人身权等，请点击“版权申诉”（推荐），也可以打举报电话：400-050-0827(电话支持时间：9:00-18:30)。
4、该文档为VIP文档，如果想要下载，成为VIP会员后，下载免费。
5、成为VIP后，下载本文档将扣除1次下载权益。下载后，不支持退款、换文档。如有疑问请联系我们。
6、成为VIP后，您将拥有八大权益，权益包括：VIP文档下载权益、阅读免打扰、文档格式转换、高级专利检索、专属身份标志、高级客服、多端互通、版权登记。
7、VIP文档为合作方或网友上传，每下载1次，网站将根据用户上传文档的质量评分、类型等，对文档贡献者给予高额补贴、流量扶持。如果你也想贡献VIP文档。上传文档

稀土掺杂znxca1-xwo4多晶的制备及上转换发光性能分析-preparation of rare earth doped zn xca1 - xwo 4 polycrystals and analysis of upconversion luminescence properties

哈尔滨工业大学理学硕士学位论文哈尔滨工业大学理学硕士学位论文 -II- -II- Abstract ZnxCa(1-x)WO4: Ho3+/Tm3+/Yb3+ polycrystals samples were prepared via high temperature solid state method. Zn0.1Ca0.9WO4 was determined as the best matrix components which was synthesized by sintering 3h under 1000℃. XRD analysis showed that there was no effect of the dopant ions on the crystal structure. Using the shift of the ultraviolet assimilation borderline to confirm the regulation of the rare-earth ions in the crystal structure. A series of Zn0.1Ca0.9WO4: Ho3+/Yb3+ samples with 4mol％ Yb3+ ions and Ho3+ ions from 0.2mol ％ ~3mol ％ were prepared. The upconversion spectra of the Zn0.1Ca0.9WO4: Ho3+/Yb3+ multi-crystals have two distinct emission peaks at 546 nm and 658 nm, which arise from the 5F4/5S2→5I8 and 5F5→5I8 transitions of Ho3+. The result showed that the intensity of upconversion luminescence were first increased then decreased with the increasing concentration of Ho3+ ions. The pump dependence indicated that the green and red upconversion emission both resulted from the two-photon process. The fluorescence lifetime of green and red light were 67μs and 106μs, respectively. Combined with the pump dependence and fluorescence lifetime, the green and red upconversion mechanism were analyzed. Zn0.1Ca0.9WO4: Tm3+/Yb3+ samples with 2mol％ Tm3+ ions and Yb3+ ions from 1mol％~8mol％ were prepared. The upconversion spectra of the Zn0.1Ca0.9WO4: Tm3+/Yb3+ multi-crystals have a distinct emission peak at 474 nm, which arise from the 1G4→3H6 transition of Tm3+. The result showed that the intensity of upconversion luminescence were first increased then decreased with the increasing concentration of Yb3+ ions. The pump dependence indicated that the blue upconversion emission resulted from the three-photon process. The fluorescence lifetime of the blue light were 82μs. Combined with the pump dependence and fluorescence lifetime, the blue upconversion mechanism were analyzed. The upconversion luminescence p