Py―GCMS研究雾化温度对电子烟油雾化主产物影响.docVIP

Py―GCMS研究雾化温度对电子烟油雾化主产物影响 　　摘要：为探索雾化温度对电子烟油雾化主产物的影响，测量了15种可充电电子烟的雾化温度等参数，利用热裂解仪模拟雾化器，在线气相色谱-质谱法分析考察了雾化温度改变对电子烟烟油雾化主产物的影响。结果表明，15种电子烟雾化温度范围为78～288 ℃，相差210 ℃；烟油在雾化过程中可以释放出1，2-丙二醇、甘油和烟碱，这3种物质组成了电子烟烟油雾化后的主要产物，三者含量之和在80、150、250、300、500和900 ℃雾化条件中分别占总量的99.66%、96.66%、99.53%、99.35%、97.25%和98.92%；雾化温度80 ℃时烟油雾化产物中未发现甘油，而且随着温度升高一直是1，2-丙二醇的相对含量高于甘油，直至雾化温度达到900 ℃时甘油的相对含量高于1，2-丙二醇。 　　关键词：雾化温度；热裂解-气相色谱/质谱联用；电子烟油；主产物 　　中图分类号：TS485；O657.62 文献标识码：A 文章编号：0439-8114（2016）15-3988-03 　　DOI：10.14088/j.cnki.issn0439-8114.2016.15.047 　　Abstract： For exploring the effects of atomization temperature on major products of electronic cigarette liquids， the main parameters of 15 kinds of rechargeable electronic cigarettes were measured，and Py-GC/MS were applied to analyze the effects of atomization temperature variation on major products of electronic cigarette liquids. Results indicated that：①The atomization temperature of 15 kinds of rechargeable electronic cigarettes were ranged from 78 ℃ to 288 ℃， the difference was 210 ℃ between the highest and lowest temperature. ②Propylene glycol， glycerin and nicotine were released from electronic cigarette liquids in the atomization process and constituted three major products after the atomization，total relative content of these three products were 99.66%，96.66%，99.53%，99.35%，97.25% and 98.92% under atomization temperature of 80，150，250，300， 500 and 900 ℃，respectively. ③Glycerin wasnt found in atomization products at atomization temperature of 80 ℃. With the increase of temperature，the relative content of propylene glycol was always higher than glycerin，but it was reversed at atomization temperature of 900 ℃. 　　Key words： atomization temperature； Py-GC/MS； electronic cigarette liquids； major products 　　电子烟由烟弹、雾化器和电池三部分构成，雾化器中的导油绳将烟弹中储存的烟油引入雾化器的加热丝上。电子烟检测到用户吸烟时，触发信号送至控制电路，连通电池，驱动加热丝加热雾化烟油产生烟气[1，2]，因不释放焦油而成为越来越受关注的燃烧性纸烟替代品。电子烟的各种物理参数决定了其雾化烟油性能，在加热丝加热雾化烟油时，直接作用于烟油的加热丝温度可能会对烟油雾化后的烟气产生一定的影响。国内关于加热雾化温度对电子烟烟油雾化主产物含量的影响报道极少，本研究对市售的15种电子烟（可充电）主要物理参数进行了测定。