硫酸装置工艺规程与岗位操作法.docx

宁夏兴尔泰集团中宁兴德化工有限公司硫酸厂 企业标准Q/HTL-2011 岗位操作及工艺规程 宁夏兴尔泰集团中宁兴德化工有限公司 2014年9月25日发布 目录 硫酸生产装置工艺操作规程································································1页 供料岗位操作法···················································································19页 桥式起重机岗位操作···········································································21页沸腾炉岗位操作法···············································································26页锅炉岗位操作法···················································································33页排渣岗位操作法···················································································42页 净化岗位操作法·················································································· 46页转化岗位操作法···················································································56页 SO2风机岗位操作法·············································································64页 干吸岗位操作法···················································································69页 成品岗位操作法···················································································79页水处理岗位操作法···············································································88页 循环水岗位操作法···············································································94页 PAGE \* MERGEFORMAT1 硫酸生产装置工艺操作规程 1.0适用范围 本标准叙述了以硫铁矿为原料，采用接触法制硫酸的生产装置、生产原理、工艺过程、生产操作和主要工艺指标等。 本标准适用于本公司200kt/a硫铁矿制酸及炉气余热发电生产装置。 2.0产品简介 2.1产品特性 2.1.1硫酸的物理性质 2.1.1.1硫酸是三氧化硫（SO3）和水（H20）的化合物，一个三氧化硫分子和一个水分子结合得到的就是纯硫酸（H2SO4），纯硫酸的分子量为98.08，是无色、无臭、透明的油状液体。 2.1.1.2硫酸的密度 硫酸的密度随浓度和温度的不同而发生变化，同一浓度的硫酸，它的密度随温度的升高而降低。因此，同一浓度的硫酸在不同温度下其密度也不同。在20℃时，93%硫酸的密度为1.82g/cm3，98%硫酸的密度为1.84g/cm3。 2.1.1.3结晶温度 硫酸水溶液的结晶温度随着硫酸含量的不同而在一个极广泛的范围内变化。 硫酸的结晶温度表（见下表） 硫酸浓度% 结晶温度℃ 硫酸浓度% 结晶温度℃ 75 -29.5 92 -17.5 76 -22.2 92.5 -22.0 77 -15.5 93 -27.0 78 -9.5 93.5 -31.2 79 -5.0 94 -31.9 80 -0.1 94.5 -26.5 81 3.3 95 -22.6 82 5.9 95.5 -16.5 83 7.5 96 -12.6 84 8.45 96.5 -9.8 85 8.0 97 -7.0 86 6.5 97.5 -3.7 87 4.6 98 -0.7 88 2.1 98.5 +1.8 89 -1.4 99 4.5 90 -5.5 99.5 7.5 9