生物质气化发电过程中焦油蒸汽催化裂解的研究-上海电力学院学报.PDF

　第 22卷第 3期 上 海 电 力 学 院 学 报 V ol. 22, No. 3 　2006 9 Journal　of　Shanghai　University　of　Electric　Pow er Sep. 　2006 　　: 006 -4729(2006)03 - 0233 -06 * , ( , 　200090) 　:, -, N iMo /A l O . , 4 2 3 , , , , . :;; :TQ 032　　　:A Study on Catalytic Cracking of Tar Component in Biomass Gasification for Electric Power Generation DOU Bin-lin, REN Jian-xing (School of Therma lPowerEnvironm entalEngineering, Shangha iUn iversity of E lectricP ower, Shanghai　200090, China) Abstract:　The catalytic crack ing of tar component from high temperature gas cleaning in biom ass gasification for electric power generation is one of the key technologies. -methylnaphthalene is chosen as a model of tar component in th is paper. The effects of reaction temperature and space velocity are studied in certain conditions. A 4-lump kineticmode,l wh ich relates the tar component conversion to coke yield, is developed to describe the catalytic cracking process of tar componen.t The kinetic parameters of the A rrhen ius’ law and the deactivation parameters are estmi ated by a non-linear regression program. The expression for the coke yield as a function of tar component conversion is show n to predict the expermi ental data. K ey words:　biomass gasification;catalytic crack ing of tar;kineticmodel 　　 . . : ,. ,、 ,, [ ～3] . 、 . , 　　:2006 - 07 -04 :()(P 302);. 234 　　　　　　　　　　　　　　　　　　　　　　2006 ,, ,, ,. , ,、 ; , (2 ) . . , ,3, .