(ZrB2-ZrO2)BN复合材料的反应热压烧结及其力学性能材料学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - 关键词 (ZrB2-ZrO2)/BN复合材料；反应热压烧结；组织结构；力学性能； 摩擦磨损机理 - - III - Abstract (ZrB2-ZrO2)/BN composites were prepared by reactive hot-pressing at 1600℃ under 30MPa for 90 min using ZrO2, B4C and C asstarting materials.Effects of sintering aids、sintering temperature and ZrB2/ZrO2 ratio on structure and properties of the composites have been systematically studied by the X-ray diffraction(XRD), scanning electron microscopy(SEM), three-point bending test, single-edge-notched beam method. The effects of applied loads, sliding velocities and ZrB2/ZrO2 ratio on tribological behaviors of (ZrB2- ZrO2)/BN composites, against GCr15 steel ball under dry sliding conditions, was revealed. Using B4C as reactant, ZrB2/BN composites were successfully achieved following the equation 2ZrO2+B4C+3C=2ZrB2+CO,.While the ZrB2/BN composites failed because of volatilization of B2O3 during sintering. The mixed sintering aids of SiO2+X promotes the densification of the composites, 8% SiO2+2%X registering as a higher relative density of 96.9% with no sintering aids and 10%SiO2, for 88% and 84% respectively. With the decrease of sintering temperature, the relative density of ZrB2/BN composites were decrease, while the mechanical properties increase remarkably Sintering at 1800℃ and 1600℃, the relative density of composites were 96.9% and 95.2%, accompany by the vickers hardness, elastic modulus, flexture strength and fracture toughness for 1.41GPa, 120GPa, 223MPa, 3.4 MPa?m1/2 and 1.63GPa, 120GPa, 286MPa, 4.2 MPa?m1/2, respectively. Smaller of BN plates and ZrB2 grains leads the formation of s decreasing intering temperaturefrom 1800℃ to 1600℃ which is beneficial to strengthen the composites. With decreased ZrB2/ZrO2 ratio, the mechanical properties of 35vol%(ZrB2- ZrO2)/BN. composites increasing firstly and then decrease, reaching a maximum value at ZrB2:ZrO2=2.5:1 with the vickers hardness, elastic modulus, flexture strength and fracture toughness of 35%ZrO2-BN