电感耦合等离子体发射光谱法同时测定婴幼儿配方乳粉中12种元素.pdfVIP

※分析检测 Journal of Dairy Science and Technology 2013, Vol.36 No.1 16 电感耦合等离子体发射光谱法同时测定 婴幼儿配方乳粉中12种元素 * 杨 洋，卢 剑 ，徐春祥，张 征 (江苏省产品质量监督检验研究院，江苏 南京 210007) 摘 要：采用电感耦合等离子体发射光谱法同时测定婴幼儿配方乳粉中K、Ca、Na、Mg、Cu 、Fe 、Mn 、Zn 、Al 、 Pb 、Cd 、Cr 12种元素的含量，对仪器工作参数进行优化。各待测元素的标准曲线的相关系数均不低于0.9995 ，方 法检出限为0.02～5mg/kg ，样品加标回收率在87.5%～106.3%之间，检测结果的相对标准偏差小于5%。该法具有快 速、准确的特点，可作为乳粉的质量控制和安全评价。 关键词：婴幼儿；乳粉；元素；电感耦合等离子体发射光谱法 Simultaneous Determination of Twelve Elements in Milk Powder for Infants and Young Children by Inductively Coupled Plasma Atomic Emission Spectrometry * YANG Yang，LU Jian ，XU Chun-xiang，ZHANG Zheng (Jiangsu Provincial Supervising and Testing Institute for Products Quality, Nanj ing 210007, China) Abstract ：A method for the simultaneous determination of twelve elements (K, Ca, Na, Mg, Cu, Fe, Mn, Zn, Al, Pb, Cr and Cd) in milk powder for infants and young children by inductively coupled plasma atomic emission spectrometry (ICP- AES) was established. Instrumental parameters were optimized. Standard curves for these twelve elements were obtained with correlation coefficients greater than 0.9995. The detection limits of the ICP-AES method for these elements were in the range of 0.02 to 5 mg/kg, and the spiked recoveries were 87.5%– 106.3% with RSD lower than 5% (n = 6). This method was rapid and accurate and could be used for quality control and safety evaluation of milk powder. Key words ：infants and young children ；milk powder ；element ；inductively coupled plasma-atomic emission spectrometry 中图分类号：O657.31 文献标志码：A 文章编号：1671-5187(2013)01-0016-03 近年来全球范围内婴幼儿配方乳粉质量安全事件频 GB 54 13.2 1—20