Zn2 离子掺杂TiO2一维纳米材料的制备及其光催化性能研究-化学工艺专业论文.docx

维 52%，TiO2 管仅为 30%。可以看出，材料改性及形貌改变对 TiO2 材料在紫外光 区的光催化性能影响较小；而在可见光区，在实验范围内所制备的各种 TiO2 纳米材 料对亚甲基兰的最高光降解率分别为：TiO2 纳米粉末 25%，TiO2 纳米纤维 32%，TiO2 纳米管 80%，Zn2+掺杂 TiO2 纳米纤维 88%，Zn2+掺杂 TiO2 纳米管 92%。由此可见， 材料的改性及形貌的改变可以提高 TiO2 材料在可见光下的光催化性能。为 TiO2 纳 米材料的实用化提供了必要的理论基础。 关键词：Zn2+掺杂；TiO2 纳米纤维；TiO2 纳米管；紫外光催化；可见光催化 Abstract TiO2 nanomaterials have board application prospects in many fields, such as photocatalytic degradation, dye sensitization, solar cells and water photolysis. However, their applications have been restricted due to wide band gap and low solar energy efficiency of TiO2. In this paper, many efforts have been devoted to increase photocatalysis activity in visible light and practicality of TiO2 nanomaterials through material modification and morphology changing. The TiO2 nanopowders, its nanofibers and nanotubes, as well as Zn2+ doped TiO2 nanofibers and nanotubes were prepared successfully. The morphology, structure and properties of the TiO2 and Zn2+ doped TiO2 nanomaterials were characterized by Termogravimetry-Differential Scanning Calorimetry (TG-DSC) analysis, X-ray diffractometry (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET specific surface areas analysis, multiangle ultrafine particle analyzer and Fourier transform infrared spectroscopy. For TiO2 nanomaterials, combining DSC and XRD analyses, the anatase TiO2 and the rutile TiO2 were developed at temperatures about 400-450oC and 450-550oC respectively during calcination of the gel. The synthesized TiO2 nanopowders had an uniform particle size distribution and an obvious agglomeration phenomenon with an average particle size of 30 nm and a specific surface area of about 40 m2/g. The diameters of the prepared TiO2 nanofibers were decreased to 100-500 nm after calcinations for 4 h at temperatures of 400oC, 450oC, 500oC and 600oC, respectively.The TEM analyses results showed that the synthesized TiO2 nanofibers were composed of small particles of 5-10 nm, and the specific su