磁性石墨烯泡的制备及对Cu2+的吸.docxVIP

201701150047 磁性石墨烯泡沫的制备及对Cu2+ 的吸 附性能 基金项目： 基金项目：国家自然科学基金项目21401170；郑州轻工业学院博士基金(2013BSJJ021) 作者简介：张琰 （1992-），女，硕士研究生。 *联系人：陈志军，教授，电话E-mail： HYPERLINK mailto:chenzj@zzuli.edu.cn chenzj@zzuli.edu.cn。 张琰1，张万俊1，董梦果1，赵翠真2， 杨清香1，陈志军1* 郑州轻工业学院 材料与化学工程学院，河南 郑州 450001；2. 河南金谷实业发展有限公司， 河南 郑州 450000） 摘要：以氧化石墨烯为前驱体，采用溶剂热法制备了磁性石墨烯泡沫(MGF)复合物。用X射线衍射(XRD)、透射电镜(TEM)及场发射扫描电子显微镜(FESEM)对其进行了表征。测定了不同铜离子初始质量浓度、反应时间和温度下复合物对水溶液中铜离子的吸附性能。结果表明：Fe3O4成功复合到了石墨烯上且为三维泡沫结构；复合物对铜离子吸附量可达49.20 mgg；吸附过程符合准二级动力学模型。磁性复合物可以借助外部磁场实现快速磁分离。 关键词：石墨烯泡沫；磁性复合物；吸附 中图分类号：X131.2；TB333 文献标识码：A Preparation and Adsorption Properties for Cu2+ of Magnetic Graphene Foam ZHANG Yan 1, ZHANG Wan-jun1, DONG Meng-guo 1 , ZHAO Cui-zhen 2, YANG Qing-xiang 1, CHEN Zhi-jun 1* School of materials and chemical engineering, Zhengzhou University of Light Industry, Zhengzhou 450001, Henan,China; 2 . Henan Jingu Industry Development Co ltd, Zhengzhou 450000, Henan, China) Abstract: In this paper, magnetic graphene foam composite was prepared via a solvent thermal method by using graphene oxide as precursor. The composites were characterized by X-ray diffraction(XRD), transmission electron microscope(TEM) and field emission scanning electron microscope(FESEM) respectively.The adsorption behavior of composites for copper ion in aqueous solution was studied at different experimental parameters(initial concentration, reaction time and temperature).The results showed that the Fe3O4 was successfully combined into the grapheme to form the a three-dimensional foam structure. The adsorption amount of copper ion was 49.20 mgg. The adsorption process was in accordance with the quasi-second-order kinetic model. Key words: graphene foam; magnetic composite; adsorption Foundation items：National Science Foundation of China21401170; Doctoral foundation of Zhengzhou University of Light Industry(2013-BSJJ021) 随着工业化进程的发展，电镀、皮革及印染等工业废水的排放导致水体中重金属离子的含量增大，对