紫外光固化纳米sio2杂化材料的制备及其性能分析-preparation and performance analysis of uv - curable nano - sio _ 2 hybrid materials.docxVIP

太原理 太原理 工大学硕士研究生论文 STUDY ON PREPARATION OF UV CURABLE NANOSILICA HYBRID MATERL生L AND THEIR APPLIED PROPERTIES ABSTRACT The UV curable coatings have developed quickly because of fast curing speed，little pollution ，energy saving advantages. However，the organic cured films have some drawbacks such as low hardness，bad abrasive resistance and low thermal stability and so on. The properties can be improved by introducing inorganic filler. Nanosilica is the inorganic filler which has the excellent prope口Y ofhigh hardness and temperature resistance. Because of the serious aggregation and hydrophilic property of nanosilica ，they can not disperse evenly in organic material ，leading to the increase of viscosity of coatings and the decrease of photopolymerization rate of coatings. Therefore，the properties of cured films such as hardness and resistance abrasion can not be improved greatly if it was directly added into the organic coatings. ln order to resolve the problem in above， the di征与rent s甘ucture polymerizable nanosilica hybrid materials were prepared by a series of experiments，which used the hydroxyl of nanosilica. The main experiments were as follows: Nanosi l ica grafted hydoxyethyl ac叩late was prepared by reaction of nanosilica with isophorone diisocyanate ，then the nanosilica bearing isocyanate group reacted with 由e hydoxyethyl acηlate. Nanosilica grafted hydoxyethyl acrylate was also prepared by esterificatoin of nanosilica and hydoxyethyl acrylate， in which p-toluenesulfionic acid was used as catalyst. The macromolecular nanosilica hybrid materials were synthesized by Ill) I l l the reaction ofthe hydoxyethyl acrγlate and nanosilica which was modified with isophorone disocyanate and poJypropyJene gJycoJ. Nanosilica hybrid pa叫cles wi由tertiary amine structure wcre prepared by reaction of nanosilica with isophorone diisocyanate，then the nanosilica bearing isocyanate group reacted with the acηlic compound containing tertiary amine structure synthesize