阻燃型石蜡储能材料制备及其应用-preparation and application of flame retardant paraffin energy storage material.docxVIP

II II TEM等手段对介孔材料进行表征，结果表明，制备的材料为介孔材料，平 均孔径2.45 nm，孔径分布集中，BET比表面积1122.5 m2·g-1，孔体积1.059 cm3·g-1，介孔材料呈薄层片状，疏松多孔结构。 然后，将制得的介孔材料作为封装材料，以熔点59.5℃，相变温度 54.4℃，相变潜热231.8 J·g-1的石蜡为相变材料，通过真空吸附法制备石蜡/ 介孔复合相变材料，采用红外分析、扩散-渗出圈法、N2物理吸附-脱附、SEM、 TEM、DSC等表征手段对复合相变材料进行表征，结果表明，介孔材料对 石蜡的最佳吸附量为50%，复合材料相变温度为56.9℃，相变潜热为75.20 J·g-1，经多次冷热循环加热，无液体泄漏现象，相变温度和相变潜热基本不 变，复合材料具有良好的稳定性。 最后，将所制备的复合相变材料添加到偏高岭土中，制备相变墙板， 考察了墙板的导热性、阻燃性和保温性能，结果表明，墙板导热系数随着 石蜡含量的增加而增加，当墙板中石蜡含量达到50%时，导热系数为1.898 W·(m.K)-1；同时，当氧浓度达到90%时，墙板不可燃；同样环境温度下， 石蜡含量越高，保温时间越长，墙板具有良好的阻燃储能性能。 关键词：相变储能 石蜡 介孔材料 阻燃 相变墙板 微波合成 III III PREPARATION AND APPLICATION OF THE FLAME RETARDANT AND PARAFFIN ENERGY STORING MATERIALS ABSTRACT With the rapid development of social economy and the rising of peoples living standards, people pursuit of the comfortable living enviroment is always accompanied by the increasing energy consumption, resulting in a series of problems of environment pollution etc. How to maintain the balance between human body comfort, energy saving, environmental protection has become a research hotspot in architectural design and energy-saving field. The use of phase change materials, which is the most effective way, has become the research focus of many scholars at home and abroad. At present, organic phase change materials were combustible, poor heat conductivity and oxidation. In addition, when the solid-liquid phase change materials happened the phase transition, the problem of liquid flowing would caused the pollution of the wall and reduced the heat storage properties of the materials. This paper took kaolin as raw materials, to prepare mesoporous materials by microwave synthesis method.Then with the mesoporous materials as carrier, paraffin as phase change materials, the paraffin / mesoporous composite phase change materials were synthesized successfully. Finally, adding it to the wall, the flame retardant paraffin phase change wallboard was prepared. PAGE PAGE VI First of all, prec