【毕业论文】Nb-Ti-SBA-15催化剂的制备及表征.docVIP

PAGE 淮北师范大学 2013届学士学位论文 Nb-Ti-SBA-15催化剂的制备及表征 系 别: 化学系 专 业: 材料化学 学 号: 20091441264 姓 名: 指 导 教 师: 指导教师职称: 教授 2012年 10 月 30 日 PAGE II Nb-Ti-SBA-15催化剂的制备 摘 要：以正硅酸四乙酯为硅源，表面活性剂P123为模板剂，通过模板法制备出介孔分子筛SBA-15，然后再以钛酸四正丁脂为钛源，Nb2O5为铌源在强酸性条件下通过浸渍法制备Nb-Ti-SBA-15催化剂，并借助XRD、SEM、IR和UV-Vis等表征手段对Nb-Ti-SBA-15进行表征，结果表明：Nb、Ti均高分散于SBA-15骨架中，制得的Nb-Ti-SBA-15催化剂保持了载体 SBA-15 高度有序的二维六方介孔结构。 关键词：介孔分子筛SBA-15; 浸渍法; Ti-SBA-15; Nb-SBA-15 The preparation and characterization of Nb-Ti-SBA-15 Abstract: Heteroatoms of Ti and Nb were effectively introduced into the framework of ordered mesoporous silica materials in strong acidic media by a two-step procedure. first, mesoporous SBA-15 were synthesized by template method, using ethyl silicate as as the Si source and surface active agent P123 as the template. The next thing was the preparation of Nb-Ti-SBA-15 using impregnation method, using tetrabutyl titanate as titanium source and Nb2O5 as niobium source. The synthesized materials were characterized by X-ray diffraction, scanning electron microscope, IR and UV-Vis spectrometer etc. The results showed that Nb、Ti were highly dispersed through the inside of SBA-15 and the prepared Nb-Ti-SBA-15 kept the highly ordered mesoporous two dimensional hexagonal structure and the mesoporous channel structure. Key words: Mesoporous molecular sieve SBA-15；Impregnation method；Ti-SBA-15；Nb-SBA-15 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc339456398 摘 要 PAGEREF _Toc339456398 \h I HYPERLINK \l _Toc339456399 Abstract Ⅱ HYPERLINK \l _Toc339456400 1 引言 1 HYPERLINK \l _Toc339456401 2 实验部分 1 HYPERLINK \l _Toc339456402 2.1仪器与试剂 1 HYPERLINK \l _Toc339456403 2.1.1仪器 1 HYPERLINK \l _Toc339456404 2.1.2试剂 PAGEREF _Toc339456404 \h 2 HYPERLINK \l _Toc339456405 2.2 实验步骤 2 HYPERLINK \l _Toc339456406 2.2.1 SBA-15的合成 2