【毕业论文】LED发光材料的固相合成及其发光性能.docVIP

周口师范学院本科毕业论文（设计） PAGE \* MERGEFORMAT7 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc388345834 摘 要 PAGEREF _Toc388345834 \h 1 HYPERLINK \l _Toc388345835 引 言 PAGEREF _Toc388345835 \h 2 HYPERLINK \l _Toc388345836 1 实验部分 PAGEREF _Toc388345836 \h 3 HYPERLINK \l _Toc388345837 1.1实验仪器及试剂 PAGEREF _Toc388345837 \h 3 HYPERLINK \l _Toc388345838 1.2实验 PAGEREF _Toc388345838 \h 4 HYPERLINK \l _Toc388345839 2 结果与讨论 PAGEREF _Toc388345839 \h 4 HYPERLINK \l _Toc388345840 2.1样品XRD的研究 PAGEREF _Toc388345840 \h 4 HYPERLINK \l _Toc388345841 2.2发光性质的研究与分析 PAGEREF _Toc388345841 \h 5 HYPERLINK \l _Toc388345842 2.2.1掺杂比例对样品发光性质的研究 PAGEREF _Toc388345842 \h 5 HYPERLINK \l _Toc388345843 2.2.2温度对荧光粉发光性能的影响 PAGEREF _Toc388345843 \h 7 HYPERLINK \l _Toc388345844 3 结 论 PAGEREF _Toc388345844 \h 8 HYPERLINK \l _Toc388345845 参考文献 PAGEREF _Toc388345845 \h 9 HYPERLINK \l _Toc388345846 致 谢 PAGEREF _Toc388345846 \h 11 LED发光材料的固相合成及其发光性能 摘 要:Eu3+离子和Tb3 +离子共掺杂的以SrMoO4为基质的荧光粉已经通过一个简单的无表面活性剂的高温固相合成的方法成功地制备了。所制备的荧光粉是纯白钨框型,四方相晶系，并且包括许多粒径在150-300nm的纳米颗粒。Eu3+、Tb3+离子共掺杂，以SrMoO4为基质的荧光粉能够体现Eu3+和Tb3+的激励与排放的特性。Tb3+离子有效地把吸收能量转移给Eu3+，使主要的发光峰值在613nm附近，Eu3+在5D0→7F2跃迁发射，该波长强度因掺杂Tb3+离子而加强。该实验对Eu3+ 、Tb3+离子的共掺杂浓度进行了良好的优化。另外，也对能量转移机制进行了研究，还对激发和发射结果进行了详细的讨论。 关键词：SrMoO4:Eu3+/Tb3+；高温固相法；发光性能 Europium-high-temperature Solid-phase Synthesis and Luminescence Properties of Terbium-doped Strontium Molydate Phosphors Abstract: Eu3+ ions and Tb3+ ions co-doped with phosphor SrMoO4 matrix have been successfully prepared by a simple surfactant-free high-temperature solid-phase synthesis methods. The white phosphor is prepared tungsten box type tetragonal crystal system, and includes a plurality of nano-particles in the particle size of 150-300nm. Eu3+, Tb3+ ions were doped with phosphor SrMoO4 matrix can reflect the characteristics of Eu3+ and Tb3+ excitation and emission. Tb3+ions efficiently absorb the energy transferred to the Eu3+, so that the main emission peak at 613nm nearby, Eu3+ 5D0 → 7F2 transit