（毕业设计论文）《无机阻燃剂粉体在聚丙烯（PP）体系中阻燃协同效应及材料的燃烧性能和结晶行为研究》.doc

中 文摘 要 本文主要研究了四种无机阻燃剂粉体，即氢氧化镁（MH）、滑石粉（Talc）、硼酸锌（ZB）、改性蒙脱土（OMT）在聚丙烯（PP）体系中阻燃协同效应。通过极限氧指数、垂直燃烧实验、锥形量热仪、差示扫描量热仪（DSC）等研究了材料的燃烧性能和结晶行为。结果表明滑石粉、硼酸锌和MH存在较好的阻燃协同效应，尤其是硼酸锌和MH并用时对PP能起到较好的阻燃效果，但是改性蒙脱土和MH的阻燃协同效应效果不是很明显。DSC试验结果表明MH能起到异相成核作用，提高材料的结晶速率并降低材料的结晶活化能。作为无机阻燃剂粉体，MH具有广阔的应用前景。 关键词：聚丙烯、氢氧化镁、滑石粉、硼酸锌、蒙脱土、阻燃 Abstract In this paper, effect of inorganic flame retardants including magnesium hydroxide (MH), talcum powder (Talc), zinc borate (ZB) and surface-modified montmorillonite (OMT) on the flammability properties of polypropylene (PP) was investigated. Limited oxygen index tests, vertical combustion measure and cone calorimeter were employed to evaluate the fire retardancy and differential scanning calorimeter (DSC) of those materials. The results indicated that synergistic effect was occurred when Talc, ZB and MH were incorporated together into PP matrix. As an inorganic flame retardant, MH has the broad application prospect. The DSC results suggested that the MH have a remarkable heterogeneous nucleation effect in the polymer matrix and decreased the activation energy (ΔE) of the mentioned samples. Key Words: Polypropylene, magnesium hydroxide, talcum powder, zinc borate, montmorillonite, flame retardant. 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc200390566 第1章 文献综述 PAGEREF _Toc200390566 \h 1 HYPERLINK \l _Toc200390567 1.1 引言 PAGEREF _Toc200390567 \h 1 HYPERLINK \l _Toc200390568 1.2 聚合物的燃烧 PAGEREF _Toc200390568 \h 2 HYPERLINK \l _Toc200390569 1.3 阻燃剂的作用机理 PAGEREF _Toc200390569 \h 3 HYPERLINK \l _Toc200390570 1.3.1 冷却机理 PAGEREF _Toc200390570 \h 3 HYPERLINK \l _Toc200390571 1. 3.2 稀释机理 PAGEREF _Toc200390571 \h 3 HYPERLINK \l _Toc200390572 1. 3.3 隔离膜机理 PAGEREF _Toc200390572 \h 3 HYPERLINK \l _Toc200390573 1. 3.4 终止连锁反应机理 PAGEREF _Toc200390573 \h 3 HYPERLINK \l _Toc200390574 1. 3.5 协同作用机理 PAGEREF _Toc200390574 \h 4 HYPERLINK \l _Toc200390575 1.4 阻燃剂的种类 PAGEREF _Toc200390575 \h 4 HYPERLINK \l _Toc200390576 1.4.1 磷系阻燃剂 PAGEREF _Toc200390576