包覆石墨与蔗糖基炭材料的大电流充放电性能研究-化学工艺专业论文.docxVIP

ABSTRACT 、 Recent years，a demand for promoting Li斗on batteries power density has been called，for 伽ey have been used as power sources for Hybrid嗣Electric Vehicles. 丁he nature of the electrode materials is of course of prima可 importance to the power properties of Li斗。n batteries. In this work， carbon anode materials were studied to improve the electrochemical p时brmance of Li斗on batteries at high current densities. Artificial graphite and sucrose were used as precursors for carbon anode materials， and the electrochemical performances ofthe electrode were investigated. ;咱 On the basis of previous studies of our laboratory，叫ua-mesophase pitch(AMP) was used to coat artificial graphite by several times，and the amount of AMP was small in every time. Electrochemical tests and SEM analysis showed that when the AMP with a mass ratio of 20% were divided into two times to coat artificial graphite ，the coating layers were the most homogeneous ，and the obtained carbon materials electrochemical properties were the best at the current density of 20mA饵， of which the discharge capacity was 366.4mAh/g and the coulombic efficiency reached 89.6% at the first cycle. While the amo叩hous coating layers of carbon materials coated by four times were fairly thick， and the reversible discharge capacity of the obtained carbon materials was 268.6mAh/g at the current density of 100mNg. ηle capacity retention ratio was up to 76.3%，which was the highest in all kinds of coated samples. In addition，sucrose-based carbon materials were obtained by adding different contents of expanded graphite to sucrose and then being pyrolyzed at the temperatures of 800.C and 1000.C. Analysis methods including SEM，TEM，and XRD were applied to study the surf如e morpholo部， and intemal struc阳res. Electrochemical ‘ testing methods including cyclic voltammetry and galvanostatic charge-discharge processes were applied to s阳dy the electrochemical performance and analyze the mechanism of lith