杯芳烃-罗丹明衍生物荧光探针性质分析-分析化学专业论文.docxVIP

贵州大学硕士研究生学位论文 -  PAGE 13 - 2. 不同结构的系列硫杂杯[4]类罗丹明衍生物（探针 2、3、4、5）均表现出对 Fe3+、 Cr3+的高灵敏性荧光及比色化学探针性质。证实了探针的作用机理为可逆型络合诱导开环 作用。探讨了修饰方式不同的硫杂杯[4]芳烃探针分子结构对离子的识别在空间位阻、屏蔽 效应、协同作用及极性作用等方面对识别性能的影响。 3. 探讨了衍生物作为电化学修饰电极修饰剂的性能。探针 2、5 具有对特定金属离子 电化学传感性能，为杯芳烃衍生物电化学传感材料基础应用进行了探索性研究。 关键词：荧光探针，氧杂杯[3]芳烃，硫杂杯[4]芳烃，罗丹明B衍生物，金属离子探针  Abstract Fluorescent probe, a kind of metal ion sensor with high performances, such as high selectivity and sensitivity, is widly used in clinical diagnoses, biology analysis, environment monitoring, etc. Metal ion, which is ubiquitous in the organism and environment, plays an important role in life sciences, environment sciences, medicine sciences and chemical processes. Also, more and more attention is paid to the influence of metal ions on environment pollution and human health. Therefore, it is important to design and synthesis chemosensors for metal ions. As the third generation molecules of calixarene is widly used to the area of fluorescent probe because of its good molecular platform. The investigation and decoration of novel Calixarene fluorescent probes have been focused recently. Rhodamine dye possesses excellent properties, such as high molar extinction coefficient and high fluorescence quantum yield. Because of the peculiar structure, rhodamine dyes become the perfect molecule model for the designation of fluorescence molecule switch, which can be used to determine metal ions, biology active substance and biological molecule. At presenet, there are many kinds of rhodamine derivation fluorescent probe, but the recognition metal ions are centralized, and the reports on the rhodamine fluorescent probes based on novel calixarene are still reported rarely. Conbined with a superior performance of rhodamine, the calixarene fluorescent probes show outstanding cooperating effect, and complexing capacity, which makes have more advantages that the other fuorescent probes. Our team decorated different calixane by rhodamine B, designed and synthesized oxacalix