丙烯酸酯类物质气味的评价研究-纺织科学与工程专业论文.docx

I万方数据 I 万方数据 丙烯酸酯类物质气味的评价研究 摘 要 随着化工行业的不断发展，人们的生活中已离不开各式各样的化学品，而化 学品的安全性也逐渐成了人们关注的焦点性话题。日常生活工作的环境中挥发性 有机物带来的异味，如涂料印花工艺中残留的丙烯酸酯单体等不仅对呼吸系统带 来了伤害，更对人体的健康造成了一定威胁。 本论文以大气污染和涂料印花工艺中常见的异味物质丙烯酸甲酯、丙烯酸乙 酯、甲基丙烯酸甲酯为主要研究对象，采用人工嗅辨法、Fox400 电子鼻技术配 合气相色谱技术对其异味强度进行定量分析。研究结果表明：丙烯酸甲酯、丙烯 酸乙酯、甲基丙烯酸甲酯气体的人工嗅辨法的最低检出浓度分别为 11ng/mL、 8.3ng/mL、0.45μg/mL；丙烯酸乙酯的气味强度最高，甲基丙烯酸甲酯的气味强 度最低；Fox4000 电子鼻的 18 根传感器中 P30/1、PA/2、T30/1、T70/2 为对丙烯 酸酯类物质敏感的传感器；丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸甲酯气体的电 子鼻法最低检出浓度分别为 5.9ng/mL、9.3ng/mL、6.1ng/mL。气味强度高的物质 人体鼻子的灵敏度高于电子鼻，而气味强度低的物质电子鼻的灵敏度更高。本实 验获得了较为系统的丙烯酸甲酯、丙烯酸乙酯、甲基丙烯酸甲酯不同强度气味的 电子鼻雷达谱图，为建立快速系统的气味评价方法奠定了基础。 关键词：异味；人工嗅辨；Fox4000 电子鼻；最低检出浓度 II万方数据 II 万方数据 STUDY ON THE ODOR OF ACRYLATES Abstract With the development of chemical industry, a variety of chemicals has been inseparable in the life of people. The security of chemicals had gradually become the concerned topic . Not only respiratory system, but also human health has been hurt by the odor of volatile organic compounds in the environment we work out. The subject of the experiment was methyl acrylate, ethyl acrylate, methyl methacrylate in air pollution and pigment printing. In this paper , the odor intensity of methyl acrylate, ethyl acrylate, methyl methacrylate was quantified by artificial olfactory method, Fox4000 electronic nose and gas chromatography. The results showed that: the respective olfactory detection limit of methyl acrylate, ethyl acrylate and methyl methacrylate was 11ng/mL, 8.3ng/mL and 0.45μg/mL. The highest intensity of odor was ethyl acrylate, the lowest intensity of odor was methyl methacrylate. The sensitive sensors of Fox4000 electronic nose were P30/1, PA/2, T30/1, T70/2. The respective electronic nose detection limit of methyl acrylate, ethyl acrylate and methyl methacrylate was 5.9ng/mL, 9.3 ng/mL and 6.1ng/mL. The sensitivity of people was higher than the electronic nose to the high odor of intensity; on the contrary, electronic nose is higher than people. Different intensities of methyl acrylate, ethyl acry