不同方法制备化学镀层的性能对比研究（毕业学术论文设计）.docVIP

摘要 化学镀镍磷合金层由于具有优良的综合性能已在各个工业部门得到了广泛的应用。目前工业上常采用的化学镀镍的操作pH有酸性和碱性两种。本次实验对试样分别进行酸性和碱性化学镀处理。分别对酸性及碱性化学镀镍层的性能进行了对比。测定了镀层在氯化钠溶液中的塔菲尔曲线和阻抗谱。测定了镀层的x射线衍射图。通过能谱分析了镀层元素组成及分布，通过扫描电子显微镜观察了镀层的表面状态。结果表明：化学镀镍层呈泡状方式生长；酸性化学镀镍镀层磷含量高于碱性化学镀镍镀层；酸性化学镀镍镀层耐蚀性也要优于碱性化学镀镍。 关键词：镍磷合金；化学镀；XRD; 塔菲尔曲线；阻抗谱；耐蚀性 Abstract Electroless nickel phosphorus alloy layer has excellent comprehensive performance, and it has been widely used in various industrial sectors. At present the operation pH which industry often used in chemical nickel plating is acidic and alkaline. This experiment specimens were acidic and alkaline electroless plating processing. Compared the performance of the acidic and alkaline electroless nickel plating. Determination of the Tafel curves and impedance spectra of the coating in sodium chloride solutions. The x-ray diffraction patterns of coating was measured. Through spectrum analysis of the coating element composition and distribution, and the surface state of coating was observed by scanning electron microscopy. The results showed that: Electroless nickel plating layer was the growth of bubble-like way；Acidic electroless nickel plating phosphorus content is higher than the alkaline Electroless Nickel；Acidic Electroless Nickel corrosion resistance is also superior to the alkaline electroless nickel plating. Keywords: Nickel-phosphorus alloy; electroless plating; XRD; Tafel curve; impedance spectroscopy; corrosion resistance 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc327439016 摘要 PAGEREF _Toc327439016 \h I HYPERLINK \l _Toc327439017 Abstrac PAGEREF _Toc327439017 \h II HYPERLINK \l _Toc327439018 1 绪论 PAGEREF _Toc327439018 \h 1 HYPERLINK \l _Toc327439019 1.1 化学镀镍概述 PAGEREF _Toc327439019 \h 1 HYPERLINK \l _Toc327439020 1.1.1 化学镀镍概念 PAGEREF _Toc327439020 \h 1 HYPERLINK \l _Toc327439021 1.1.2 化学镀镍的特点 PAGEREF _Toc327439021 \h 1 HYPERLINK \l _Toc327439022 1.1.3 化学镀镍的发展与应用前景 PAGEREF _Toc327439022 \h 3 HYPERLINK \l _Toc327439023 1.2 化学镀镍的机理 PAGEREF _Toc327439023 \h 7 HYP