溶胶凝胶法制备纳米铟锡氧化物--毕业论文设计.doc

溶胶凝胶法制备铟锡氧化物及其影响因素 2 PAGE 3 中文摘要 Ⅰ 溶胶-凝胶法制备纳米铟锡氧化物及其影响因素 摘 要 纳米技术和纳米材料的科学价值和应用前景已经逐渐被人们所认识。铟锡氧化物是一种重要的铟深加工产品，是当今信息产业重要的电子材料，主要运用于液晶显示、太阳能电池和节能建筑等领域。因此，对铟锡氧化物的研究具有十分重要的意义。 溶胶-凝胶制备技术是一种操作简单容易的常用制备手段。该法制备的产物具有产物均匀性好，煅烧温度低，产品纯度高等优点。因此，本文选用溶胶-凝胶法制备纳米铟锡氧化物。 本实验选用硝酸铟［In(NO3)3·4.5H2O］和四氯化锡［SnCl4·5H2O］为前驱体，乙酰丙酮为螯合剂，采用溶胶-凝胶法成功制得具有多面体形貌的纳米铟锡氧化物；并用XRD、SEM、TEM和UV-Vis等技术手段对其组成、形貌、结构及光学性能进行表征，结果表明所得产物在200-400nm范围内对光有强烈的吸收。 通过改变体系中In3+和Sn4+的摩尔比进行对比实验，研究其对铟锡氧化物形貌和光学性能的影响。 关键词：纳米结构；铟锡氧化物；溶胶凝胶法合成 PAGE II PAGE 3 ABSTRACT PAGE I Sythesis of indium tin oxide nanostructure by sol-gel and the influnence factors ABSTRACT Nano-technology and nano-materials has been gradually recognized due to their scientific and application prospects. Indium Tin Oxide (ITO), an important electronic materials in information industry, has potential applications in LCD screen, solar cells, energy-saving construction and other relative fields. Therefore, it is very interesting to research on indium tin oxide. Sol-gel technology is a simply and commonly method for synthesizing nanomaterials. The syntheiszed products own good uniformity, lower burning temperature, solid-state temperature, high purity, and so on.. Therefore, sol-gel is chosen as a chief synthetic method in our experiments. In this experiment, nanostructured indium tin oxide were synthesized successfully via sol-gel process using In(NO3)3·4.5H2O and SnCl4·5H2O as the precursor, acetylacetone as the chelating agent. The as-obtained products were investigated by X-ray diffractometer (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM) and ultraviolet-visible light absorption (UV-Vis). The results show that the all the products have strong absorption to the light of 200-400 nm. In this thesis, the morphologies and optical properties of the indium tin oxide were studied by changing the mol-ratio of In3+ and Sn4+ in the comparative experiments. Key words: nanostructures; Indium Tin Oxide (ITO); Sol