有机硅改性丙烯酸酯乳液的合成及应用--毕业论文设计.docVIP

I 有机硅改性丙烯酸酯乳液的合成及应用 摘要 以八甲基环四硅氧烷（D4）为原料，用非离子型乳化剂AEO-3、AEO-7、 AEO-9和阴离子乳化剂十二烷基苯磺酸钠（SDBS）制备有机硅乳液，探讨了乳 化剂种类、乳化剂配比等因素对有机硅乳液稳定性的影响。采用连续滴加法，将 50g甲基丙烯酸甲酯、丙烯酸正丁酯、丙烯酸混合单体以及引发剂滴加到100g 有机硅乳液中，合成了有机硅-丙烯酸酯乳液，探讨了有机硅改性丙烯酸酯乳液 的优化工艺。设计了六种不同玻璃化温度(理论值)的硅-丙乳液，并与常用的有机 硅类、石蜡类、有机氟类拒水整理剂进行比较。 实验结果表明：当乳化剂SDBS：AEO-3：AEO-7：AEO-9的质量比为1： 0.6：0.7：0.4时能制备出稳定的有机硅乳液。有机硅改性丙烯酸酯乳液的优化工 艺为：单体滴加时间为180min、温度为60℃、引发剂用量为单体的0.6%～0.7%、 搅拌速度为200～400rpm。织物经硅-丙乳液整理后拒水效果达到2～3级，好于 有机硅类，略低于石蜡类、低于有机氟类。整理后的织物经20次水洗后，经硅- 丙乳液整理后的织物拒水效果达到2级，好于有机硅类、石蜡类，低于有机氟类。 经硅-丙乳液整理后织物的硬挺度随着Tg(理论值)的升高而升高，经整理后的织 物白度均无明显变化。 关键词：硅-丙乳液；乳液聚合；改性；单体；拒水性能；织物整理II Synthesis and Application of Silicone Modified Acrylate Emulsion Abstract AEO-3,AEO-7,AEO-9 and SDBS were employeed as the emulsifiers of Octamethylcyclotetrasiloxane.The type and the ratio of emulsifiers were determined for the preperation of stable silicone emulsion.Through the method of continuous titration,50g of methacrylate、butyl acrylate、acylic-acid and initiator should be dropped into100g stable silicone emulsion,then silicone modified acrylate emulsion could be prepared,the optimized process condition was also discussed.The properties of six kinds of silicone-acrylate emulsion samples were designed to compare with agents of organo-siliconthe、paraffin、organo-fluoride. The results showed:When the mass ratio of SDBS and AEO-3,AEO-7,AEO-9 was 1:0.6:0.7:0.4,stable silicone emulsion could be prepared.The optimized process condition of silicone modified acrylate emulsion could be prepared when the dropping time of monomer was 180min,the temperature was 60℃,the contents of initiator was 0.6%～0.7%(based on monomer mass),the stirring rate was 200～400rpm.Finished fabric showed the results that the water repellent of fabric finished by silicone-acrylate emulsion reached 2～3 grade,higher than organo-silicon agent, slightly lower than paraffin agent,lower than organo-fluoride agent.Finished fabric washed 20 times showed that the water repellent of Fabric finished by silicone-acrylate emul