原油饱和烃指纹的内标法分析-分析化学.PDF

35 ( FENXIHUAXUE ) 8 2007 8 Ch inese Journal ofAnalytical Chem istry 1121~ 1126 * 王鑫平 孙培艳 周青 李 梅 曹丽歆 赵玉慧 (, 266033) ( ) , F1, 48, , , 32 1. 2% ~ 7. 4% ; 45 2. 5% ~ 9. 2% , 73% ~ 116% ; 84% ~ 106% ; 71 0 L g/ g; 0. 65 L g/g, , , , , , , , , 1 , - [ 1~ 5] , [ 6 ~ 8] , , ; , , , [ 9] (), -, m /z 191m /z 217, [ 10] , , 19, -, , (), , 2 2. 1 GCMS-QP2010- (), DB-5M S ( 30 m @ 0. 25 mm, 0. 25 Lm); ()()( 0. 154~ 0. 098 mm, ) ( sepu lco); C D ( Chem service); 5A- ( Sigma 24 50 ); AAA20R 24R-ethylcholestane( Ch iron AS ); 17B(H ), 21A(H )-hopane( Ch iron AS) 2. 2 0. 2 g, 10 mL, 3000 r/m in 0. 2 mL , 3 g( 0. 5 cm), 15 mL( F1) 2006-11-09; 2007-02-07 / 0 * E-m ail: csy q@ 163. com 35 1122 15 mL( 1B1)( F2) F 1, 100 LL ( C D ) 100 LL ( 5A-), 1mL; F2 24 50 , 2. 3 2. 3. 1 : , 1. 37 mL /m in; : 290e ; : 230e ; : 1 LL; 6e /m in : ; : 50e ( 2 m in) 300e ( 16 m in) 2. 3. 2 : EI; : 200e ; : 2. 4 , , 2. 5 5 , ( c ) ti ( c , c , c , c , c ), (c ) , t1 t2 t3 t4 t5 IS (A /A , A /A , A /A , A /A , A /A )( c /c , c /c , c /c , c /c , c /c ), IS t1 I