东苕溪水体氮、磷形态分析及其空间差异性-北京玛格泰克科技发展有限.PDF

中国环境科学 2016,36(4) ：1181~1188 China Environmental Science 东苕溪水体氮、磷形态分析及其空间差异性 徐兵兵 1,卢 峰 1,2,黄清辉 1,李建华 1* (1. 同济大学环境科学与工程学院,上海 200092 ；2.上海市政工程设计研 究总院(集团)有限公司,上海 200092) 摘要：于 2009~2011 年在东苕溪开展了 4 次全流域野外调研,系统分析了东苕溪水体氮、磷形态特征及其空间差异性.东苕溪可分为上游、 中-上游、中-下游 3 个河段,分别具有山溪性河流、城镇影响河流、平原型河道特征.结果表明,水体中氮以溶解态为主,硝态氮(NO3--N)是 溶解态总氮(DTN)的主要形态;颗粒态磷比例略高,溶解态总磷(DTP) 的相对贡献沿程降低.溶解态有机氮(DON)、磷(DOP)分别占 DTN 和 DTP 比例的 22%、42%,且 TN 与 DON 、TP 与 DOP 之间显著正相关.中-上游河段的氨氮(NH4+-N),DOP 和溶解性正磷酸盐(PO43--P)含量 最高且电导率与 NH4+-N 、DOP 之间存在显著正相关,表明城镇污、废水排放影响水体氮、磷含量及形态特征;浊度与各形态磷之间均存在 极显著正相关,河段下游开矿、行船及挖沙引起的矿质颗粒输入或沉积物再悬浮是磷素的重要来源,但水体中部分溶解态磷吸附在矿质颗 粒表面形成胶体物质,导致中-下游河段 DTP 略有降低. 关键词：东苕溪；有机氮；有机磷；空间差异性 中图分类号：X522 文献标识码：A 文章编号：1000-6923(2016)04-1181-08 1 1,2 Forms of nitrogen and phosphorus and their spatial variability in East Tiaoxi River. XU Bing-bing , LU Feng , HUANG Qing-hui1, LI Jian-hua1* (1.College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China ；2.Shanghai Municipal Engineering Design Institute (Group) Corporation Limited, Shanghai 200092, China). China Environmental Science, 2016,36(4)：1181~1188 Abstract ：From 2009 to 2011, four field surveys were carried out in East Tiaoxi River watershed. The forms of nitrogen and phosphorus and their spatial variability were analyzed. East Tiaoxi River could be divided into three sections, namely upper reach, middle-up reach and middle-lower reach, and characterized by hilly river, river influenced by urban and plain river, respectively. The results showed that dissolved nitrogen was the main nitrogen species in water, and nitrate (NO3- N) was the major form of dissolved total nitrogen (DTN) species. Meanwhile, phosphorus in part