（毕业学术论文设计）-水热法制备形貌可控ZnO.docVIP

CHANGSHA UNIVDRSITY OF SCIDNCD TDCHNOLOGY 毕业设计（论文） 题目： 水热法制备形貌可控ZnO 学生姓名： 学 号： 班 级: 无机 专 业： 无机非金属材料工程 指导教师：  水热法制备形貌可控ZnO 摘要 以乙酸锌（Zn(CH3COO)2）为锌源，尿素（CO(NH2)2）为碱源，非离子型聚氨酯（PU）为模板，采用水热法制备了碱式碳酸锌（Zn5(CO3)2(OH)6）前驱体。在400℃下进一步煅烧前驱体2h，即获得氧化锌粉末。用粉末X射线衍射、视频显微镜及扫描电镜研究了产物的结构和形貌，结果表明，以PU为模板制备的氧化锌可以获得纳米六方形片状结构形貌，PU的加入可以有效减小氧化锌的晶粒尺寸。进一步研究反应时间对产物结构的影响， 结果表明采用IPDI（N-4）型聚氨酯为模板、反应时间为20小时能得到较好的ZnO颗粒，并且随着反应时间的延长，晶粒尺寸不断增大。XRD及热分析结果显示，采用水热法制备的（Zn5(CO3)2(OH)6）前躯体在400℃以下完全分解成ZnO。 关键词： 非离子型聚氨酯；碱式碳酸锌；氧化锌；水热法  HYDROTHERMAL PREPARATION TECHNIQUE OF ZnO CRYSTAL ABSTRACT The precursors, zinc carbonate (Zn5(CO3)2(OH)6)，were synthesized in hydrothermal conditions with HYPERLINK javascript:showjdsw(showjd_0,j_0)zinc acetate (Zn(CH3COO)2) as zinc source, urea (CO(NH2)2) as alkaline source, and HYPERLINK /dict_result.aspx?searchword=%e9%9d%9e%e7%a6%bb%e5%ad%90%e5%9e%8b%e8%81%9a%e6%b0%a8%e9%85%aftjType=sentencestyle=t=nonionic+polyurethanenonionic polyurethane (PU) as template. Zinc oxide (ZnO) powders were obtained when the synthesized precursors were HYPERLINK /dict_result.aspx?searchword=%e7%85%85%e7%83%a7tjType=sentencestyle=t=calcinedcalcined under 400℃ for 2h. The morphology and structure of ZnO powders were investigated by X-ray diffraction (XRe) and scanning electron microscope (SEM). The result showed that the morphology of ZnO synthesized by using Polyurethane as a template was disk-like with hexagonal a HYPERLINK javascript:showjdsw(showjd_0,j_0) lamellar structure, PU could reduce efficiently the nanoparticle size of ZnO. The influence of the reaction time , the type of the PU on the product morphology were also investigated. It was showed that the best result can be obtained when IPDI(N-4) was used as a template and reaction time was 20h. And the grain size is getting larger as the reaction time is getting longer. Key word: HYPERLINK /dict_result.aspx?searchword=%e9%9d%9e%e7%a6%bb%e5%ad%90%e5%9e%8b%e8%81%9a%e6%b0%a8%e9%8