以氮为中心交联接枝共聚淀粉黄原酸盐制备工艺优化和产物.PDFVIP

16 2011, Vol. 32, No. 24 食品科学 ※工艺技术 以氮为中心的交联接枝共聚淀粉黄原酸盐 制备工艺优化及产物表征 夏 璐，鲁栋梁，胡伊旭，金 帅 (广西民族大学化学与生态工程学院，广西林产品开发与应用重点实验室， 化学与生物转化工程新技术广西高校重点实验室，广西南宁 530006) 摘 要：以可溶淀粉和原乙酸三甲酯进行缩醛反应生成淀粉环酯，在氨水中交联、接枝共聚、磺化合成出以氮为 中心的交联接枝共聚淀粉黄原酸盐(dithioamino starch xanthogenate ，DSX) 。通过正交试验设计方法优化制备条件， 结果表明：原料淀粉10g 、交联剂(环氧氯丙烷) 1.77g 、引发剂(过硫酸铵)0 .053g 、接枝单体(丙烯酰胺)3 .37g 和二硫 化碳6 .30 g ，合成的产物(D SX ) 对模拟废水中Cu 2+ 的去除率达到9 8 .5% 。采用红外图谱、元素分析、核磁、热分 析、扫描电镜等多种手段对产物进行表征。 关键词：淀粉；接枝共聚；吸附；金属离子；表征 Optimal Preparation of Dithioamino Starch Xanthogenate and Its Characterization XIA Lu ，LU Dong-liang ，HU Yi-xu ，JIN Shuai (Key Laboratory of Development and Application of Forest Chemicals of Guangxi, Key Laboratory of Chemical and Biological Transforming Process, College of Chemistry and Ecological Engineering, Guangxi University for Nationlities, Nanning 530006, China) Abstract ：In order to synthesize a novel dithioamino starch xanthogenate (DSX), the acetalization reaction between soluble starch and trimethyl orthoacetate was carried out to form starch acetal-3,6 ring ester, followed by cross-linking in aqueou s ammonia, graft copolymerization with acrylamide and sulfonation. Using orthogonal array design, the optimal reaction system was determined to consist of: 10 g of starch, 1.77 g of cross-linking reagent, 0.053 g of initiator, 3.37 g of graft monomer and 6.30 g of carbon disulfide. The synthesized product could remove 98.5% Cu2+ from simulated wastewater. Further, its structure was characterized by FT-IR, elemental analysis, nuclear magnetic resonance (13C-NMR and H-NMR), thermogravimetric analy sis (TG) and scanning electron microscope (SEM). Key w ords ：starch ；graft cop olymeriza