Sulfinert技术介绍.pdfVIP

Advantages to Using Inert, Coated Components for Sampling, Storage and Transfer of Organo-Sulfur Compounds Gary A. Barone, David Shelow, David Smith /norleans/2226p.pdf Exhibited at Pittcon 2000, New Orleans, Louisiana. Introduction • What to consider in sample flowpaths • How to shield metal surfaces • Examples of flowpath components – Sampling – Holding – Transfer • Advantages to using coatings In this presentation we will discuss the need for inert sample flowpaths for analysis of reactive chemical species. In particular the reduction of activity of metal surfaces by application of an inert thin-film coating. This presentation will focus on the use of the TM Sulfinert coating, a proprietary thin-film coating developed by Restek Corporation. This presentation will show the importance of passivated system components when transfer of sulfur compounds is required. We will demonstrate the need for activity-reduction in these components and show specific examples of the effectiveness of the layer. Flowpath Considerations • Transfer and holding of adsorptive or reactive species such as sulfurs, alcohols or pharmaceuticals • Low-level analysis • All Components: – Tubing – Valves – Cylinders • All Wetted Flowpath Components For the analysis of reactive or adsorptive species, the metal components of sampling and storage hardware often interfere in proper quantitation. For example, hydrogen sulfide will adsorb strongly to stainless steel components in instruments. When adsorption occurs proper quantitation of concentration is impossible. When trying to quantitate trace levels of any chemical species