掺杂ZnS纳米颗粒的合成和表征-无线电物理专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II II Abstract Nano particles just called quantum dots, are widely used in Biomarkers, Photoelectric sensor, Trace chemical detection and so on. This paper mainly studies the hot inject preparation doping ZnS nanoparticles and doping ZnS/PMMA bulk. By introducing different doping ion and different doping concentration to study different doping ions on the luminescence properties of ZnS influence. Firstly, This paper adopts hot inject successfully synthesis of ZnS:Mn/ZnS nano particles. The average particles size for nanoparticles is 3.77nm. the nanoparticles are single dispersion. Through a variety of means to study the preparation conditions on the influence of the optical properties of nanoparticles. When doping concentration is Mn:Zn=6%, inject temperature of S is 230℃, growth temperature of core is 280℃, growth time of core is 20 min, growth time of shell is 50 min, the preparation of ZnS:Mn/ZnS nanoparticle’s luminescent properties is best. ZnS:Mn/ZnS nanoparticle’s absorption peak is 310nm. Photoluminescence peak is 588nm. QY is 23.64%. After annealing nanoparticles surface organic matter will reduce. But particle size will increase. Luminous intensity will decrease. ZnS:Mn/ZnS nanoparticles have weakly magnetic property. Secondly, We used MMA formed PMMA by chemical self-assembly to ZnS:Mn/ZnS nanoparticles fixed in bulk. Through a variety of means to study the synthesis conditions on the ZnS:Mn/ZnS/PMMA influence. When initiator concentration is 2%, preliminary polymerization time is 40 min, polymerization time is 20h, completely polymerization time is 150 min, the preparation of ZnS:Mn/ZnS/PMMA is best. ZnS: Mn/ZnS/PMMA’s absorption peak is 310nm. Photoluminescence peak is 588nm. QY is 14.73%. ZnS:Mn/ZnS/PMMA has a weak magnetic property. Lastly, we adopts hot inject successfully synthesis of ZnS:Cu/ZnS nanoparticles. Used stearic acid copper for precursor and washing twice after preparation is best.