多潘立酮对黄铜在两种含氯溶液中的缓蚀行为研究化学专业论文.docxVIP

重庆大学硕士学位论文英文摘要 重庆大学硕士学位论文 英文摘要 PAGE PAGE IV ABSTRACT Brass alloy which mainly consisted of copper and zinc was widely applied in modern industry due to its excellent mechanical and technological properties. However， the brass was corroded faster in the aqueous solution containing chloride ions. Therefore the study on environment-friendly corrosion inhibitor with excellent performance to brass in chlorine-containing solution was paid much attention. In this paper, methods including polarization curve, AC impedance, weight loss, scanning electron microscope and quantum chemical calculation were used to evaluate the corrosion inhibition of Domperidone on brass in 1mol/L HCl and 3.5%NaCl solution, respectively. The results showed that the corrosion rate of brass in 1mol / L HCl solution was greater than that in 3.5% NaCl solution. Domperidone had good inhibition effect on corrosion of brass alloy both in 1mol / L HCl solution and 3.5% NaCl solution. The inhibition effect in 1mol/LHCl solution was much more remarkable than that in 3.5% NaCl solution. In 1mol / L HCl solution, the inhibition efficiency on brass was increased with the addition of Domperidone firstly, and then reached the peak with the addition of Domperidone 150mg / L, but then the inhibition efficiency decreased with much higher addition of Domperidone. The highest inhibition efficiency was 91.5%. The inhibition efficiency of Domperidone on brass in 3.5% NaCl solution has the same tendency with that in 1mol / L HCl solution. The highest inhibition efficiency was 88.5% in 3.5% NaCl solution with 150mg / L Domperidone. It was assumed that there were imidazoline structure and nitrogen-containing six-member ring in Domperidone molecular that could supply lone pair electrons to bond with the lowest unoccupied molecule orbital (LUMO) of copper and absorb on the surface of brass. So Domperidone molecules and chloride ions, water molecules would compete to absorb on the surface of brass due to the nitrogen, ox