基于半刚性羧酸配体合成.docVIP

长春师范学院本科毕业论文（设计） PAGE PAGE III 长春师范学院本科毕业论文（设计） 分 类 号： TP391 学号：1019140111 学号：12345678910 本科毕业论 基于半刚性羧酸配体的 二价锰配位聚合物的合成 Based on a semi-rigid dicarboxylic acid and N-donor ligands with versatile conformations 姓 名： 王家志 专 业： 化学 指导教师姓名： 郭华东 指导教师职称： 讲 师 2014年5月 摘 要 近十年来，配位聚合物由于其新颖的拓扑构型、空间结构，以及在磁性、发光、吸附和催化等领域的应用前景，一直受到人们的广泛关注。金属有机骨架化合物是由无机金属中心或者金属簇的次级结构单元通过刚性的或者柔性的有机配体连接成的一维、二维或三维晶态的结构。作为多孔材料家族的新成员，其凭借独特的结构可裁剪性、多样的拓扑结构和在离子交换、气体分离、催化、气敏以及光、电、磁、手性拆分等领域的潜在应用而引起研究者的极大兴趣。但是，金属有机骨架化合物的定向合成仍然是一个遥远的目标。合理地选择配体结构和中心金属离子对于构筑配位聚合物起着决定性的作用。本论文采用半刚性羧酸作为配体与金属锰离子共同构建了一个结构新颖的配位聚合物。并对其结构和性能进行了初步的表征。 关键词：配位聚合物 拓扑结构 磁性 长春师范学院本科毕业论文（设计） Abstract Over the past decades, coordination polymers, due to its novel topology configuration, spatial structure, as well as the prospects in areas such as magnetism, luminescence, adsorption and catalytic, have recently attracted wide-spread interest. Metal-Organic Frameworks (MOFs) are HYPERLINK /wiki/Crystal \o Crystal crystalline compounds consisting of metal ions or clusters coordinated to often rigid organic or flexible molecules to form one-, two-, or three-dimensional structures. MOFs, as a novel type of porous materials, have been attracted a great deal of interest due to their flexible tailoring, varying topologies and potential applications in ion-exchange, gas separation, catalysis, gas sensor in combination with optics, electrics, magnetism and enantioselective separation. However, the “true” engineering of MOFs remains a difficult challenge.In this thesis, interacting with fluorene acid which functions as a ligand,manganese metal ions build two potential magnetic properties of coordination polymers. It is the impact of the organic template agent that has been depicted in detail ,adding a brief introduction of their structures and properties . Key Words: Coordination