改性PAN非织造布铁配合物可见光降解甲醛气体-北京玛格泰克科技.PDF

中国环境科学 2016,36(5) ：1353~1359 China Environmental Science 改性 PAN 非织造布铁配合物可见光降解甲醛气体 韩 旭,韩振邦,赵晓明* (天津工业大学纺织学院,天津 300387) 摘要：使用盐酸羟胺对聚丙烯腈非织造布(nPAN)进行了化学改性,并将所得改性聚丙烯腈非织造布(AO-nPAN)与 Fe(III)配位制得改性聚丙 烯腈非织造布铁配合物(Fe-nPAN),分别使用扫描电镜(SEM)、傅立叶红外光谱(FTIR)、X 射线衍射(XRD)和 UV-Vis 吸收光谱对 Fe-nPAN 进行了表征,然后将其作为光催化剂应用于甲醛气体的氧化降解反应中.结果表明:提高 Fe(III)初始浓度、反应温度和 AO-nPAN 的增重率 都能够增加 Fe-nPAN 的 Fe(III)配合量.Fe-nPAN 中偕胺肟基团与 Fe(III)发生了配位反应,使其在可见光区有明显的吸收带.增加 Fe(III)配合 量和可见光强度都能够促进甲醛的降解反应,而且与 PAN 纱线制备的铁配合物催化剂相比,Fe-nPAN 明显具有更高的催化活性. 关键词：PAN 非织造布；铁离子；配合物；光催化；甲醛 中图分类号：X701.7,TS174.3 文献标识码：A 文章编号：1000-6923(2016)05-1353-07 Preparation of modified PAN nonwoven Fe complex and its photocatalytic performance on formaldehyde * degradation. HAN Xu, HAN Zhen-bang, ZHAO Xiao-ming (Division of Textiles, Tianjin Polytechnic University, Tianjin 300387, China). China Environmental Science, 2016,36(5)：1353~1359 Abstract ：Polyacrylonitrile nonwoven (nPAN) were chemically modified with hydroxylamine, and the obtained amidoximated polyacrylonitrile nonwoven (AO-nPAN) were coordinated with Fe (III) to prepare modified nPAN supported Fe complexes (Fe-nPAN). The complexes were characterized using Scanning electron microscope (SEM), Fourier Transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and UV-vis absorption spectra, and then employed as photocatalysts in the oxidative degradation of formaldehyde. The results indicated that increasing Fe (III) concentration, reaction temperature and weight gain rate of AO-nPAN led to higher Fe (III) content of Fe-nPAN. The amidoxime groups were coordinated with Fe (III) in Fe-nPAN, which gave the catalyst a remarkable absorption in the visible regio