储粮熏蒸剂残留的影响因素及其分析方法的研究-分析化学专业论文.docxVIP

摘要 4. 将熏蒸剂残留检测分析技术应用到其残留的影响因素的分析中，建立了一个简单 的熏蒸模拟方法，初步探索了时间，温度，温度条件对熏蒸剂残留的影响。结果表明， 温度和湿度等环境因素对残留有…定的影响，而长时间的通风散气可有效的消除残留。 关键词t 熏蒸剂，顶空气相色谱，加速溶剂萃取，固相微萃取 日 Abstract Abstract With increasing attention on food safety issues，the problem of fumigants residues in raw cereals has roused extensive concem. By now，there are some methods for determining fumigants residues in agricultural crops. However most of them usually require large amounts of solvent and time-consuming. In this way，让is necessary to develop a :fi t and sensitive method ωanalyze 由e residues in raw cereals. In this essa弘 with the aim to develop sample prepar旧ion methods for analyzing raw cereals samples，several pretreatment procedures，such 附 ultrasonication 邸sisted extraction (UAE)，accelerated solvent extraction (ASE) and the solid phase microextraction(SPME) were. studied，which was proved to be practical and reliable for the residues analysis wi由HS-GC-ECD. The thesis mainly includes the following four parts. The method for determination of bromomethane residues in raw cereals by static headspace gas chromatography wωestablished. The whole sampling process，using water as extraction solvent，only including an ultrasonic assisted extraction step and a static headspace step，can be completed within 30min. Limits of detection w;ωless than 0.016 mglkg. Recoveries of spiked samples were 94.79%.107.03% ，with relative standard deviations (RSD) of 4.3%嗣8.3%.The results indicated th削白is method was easy in operation with acceptable sensitivity，recovery and reproducibi1ity. Accelerated solvent extraction (ASE) and ultrasonic assisted extraction were compared for their effectiveness in the extraction of fumigants residues from raw cereals. The ASE parameters (temperature ，extraction time，number of cycles and solvent composition) were optimized in order to maximize the amount of fumigants extracted.ηlen the HS-GC-ECD W邸 applied to the quantitative analysis after extractions. E班ects of di