4-分子结构-学原理.pptVIP

Bond Type and DEN Hybrid Orbitals and VSEPR Write a Lewis structure (/Determine LP ) Use VSEPR to predict electron geometry. Select the appropriate hybridization. Example: H2+ ,H2 ,He2 and He2+ O2, F2 N2 BO = (1-0)/2 = ? H2+ BO = (2-0)/2 = 1 H2 BO = (2-1)/2 = ? He2+ BO = (2-2)/2 = 0 He2 BO = (e-bond - e-antibond )/2 ? NO+ N2 CO 等电子体(isoelectronic) MO Diagrams of Heteronuclear Diatomics CO 1.128 CO+ 1.115 Illustration of molecular orbital O2 [(s1s)2(s*1s)2 (s2s)2(s*2s)2 (s2px)2 (p2py)2 (p2pz)2(p*2py)1 (p*2pz)1] or O2 [KK (s2s)2(s*2s)2 (s2px)2 (p2py)2 (p2pz)2(p*2py)1