反应工程基础程易chpt13-internaldiffusion-72640638.ppt

也可以直接接分 * Effectiveness factor for n order reaction * For large values of the Thiele modulus for an n order reaction, For large values of the Thiele modulus for an first order reaction, * When a reaction is exothermic and non-isothemal, the effectiveness factor can be significantly greater than 1. Multiple stead-states can exist for values of the Thiele modulus less than 1 and when ? is greater than approximately 0.2. There will be no multiple steady stares when the criterion developed by Luss is fulfilled. * Rate without any diffusion effects =1 for no diffusion resistance This sphere expression is a good approximation for all particle shapes Characteristic length ? = Effective factor, which accounts for the resistance to pore diffusion ?1 = Thiele modulus, useful for predicting reactor behavior from known kinetic information, thus known k’’ CWP = Weisz modulus, useful for predicting experiments since it only includes observations Effective diffusion coefficient in porous solids with where 12.3 Falsified kinetics * A log-log plot of the measured rate of reaction -rA, as a function of the gas-phase concentration CAs, (external mass transfer is eliminated, thus CAs=CAb) Relate this measured reaction order n to the true reaction order n. * Using the definition of the effectiveness factor: For large values of the Thiele modulus, ? is: (external mass transfer is eliminated, thus CAs=CAb) * Overall Effectiveness Factor When both internal AND external diffusion resistances are important (i.e., the same order of magnitude), both must be accounted for when quantifying kinetics. It is desired to express the kinetics in terms of the bulk conditions, rather than surface conditions: Overall Effectiveness Factor Accounting for reaction both on and within the pellet, the molar rate becomes: For most catalyst, internal surface area is significantly higher than the external surface area: ac is the external surface area per unit reactor volume Molar rate of mass