反应工程基础程易chpt15-fluidizedbedreactor-2013-7837010000.ppt

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反应工程基础程易chpt15-fluidizedbedreactor-2013-7837010000.ppt

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Reaction behavior in a fluidized bed * For nth order, constant-volume catalytic reaction The reaction rate in the cloud: The reaction rate in the emulsion: where ke, kc and kb are the specific reaction rates in the emulsion cloud, and bubble, respectively. The reaction rate in the bubble phase: * Balance on bubble phase Balance on cloud and wake phase: Mole balance on the bubble, the cloud, and the emulsion * Balance on emulsion phase Assuming that the derivative terms on the left-hand side of the material balances on the cloud and emulsion are negligible in comparison with the terms on the right-hand side, then Partitioning of the catalyst * kb, kc, and ke are dependent on the partitioning of the catalyst where kcat is the specific reaction rate per volume of catalyst. * The volume of cloud and wakes per volume of bubble is The value of ?b ranges between 0.001 and 0.01, with 0.005 being the more typical number. * In essence, given umf, ?mf, u0, ?, and the effective bubble size in the bed db, this model tells you all the other properties of the bed-flows, region volumes, interchange rates, and consequently reactor behavior. Design equation of the fluidized bed To arrive at our fluidized-bed design equation for a first-order reaction, we simply express both the concentration of A in the emulsion, CAe, and in the cloud, CAc, in terms of the bubble concentration. * First, we use the emulsion balance to solve for CAe in terms of CAc. * Solving for CAc in terms of CAb gives: We now use this equation to substitute for CAe in the cloud balance * We now substitute for CAc in the bubble balance: * * Expressing CAb as a function of X, * Resistance to reaction in the bubble Resistance to reaction in the bubble Resistance to reaction in the bubble Resistance to transfer between bubble and cloud Resistance to transfer between cloud and emulsion * * Although a single particle will be entrained by a stream of gas flowing faster than ut, this finding does not extend to a fluidiz