表面活性素分子结构对其胶束化行为的影响-物理化学学报.PDF

物理化学学报(Wuli Huaxue Xuebao) 1128 Acta Phys. -Chim. Sin. 2011, 27 (5), 1128-1134 May [Article] 表面活性素分子结构对其胶束化行为的影响 李 翌 邹爱华 叶汝强 牟伯中* (华东理工大学应用化学研究所, 上海200237) 摘要: 采用表面张力、界面张力、荧光、动态光散射(DLS)和冷冻刻蚀电镜(FF-TEM)等方法, 研究了由Bacillus subtilis HSO121所产生的一组表面活性素的胶束化行为. 通过对表面活性素溶液表面张力、表面活性素对水/ 正己烷界面张力的影响、表面活性素胶束微极性以及胶束粒径和形态的研究, 发现随着表面活性素脂肪链长度 的增加, 其表界面活性增强, 溶液中趋向于形成更大的聚集体. 关键词: 表面活性素; 胶束; 荧光; 动态光散射; 冷冻刻蚀电镜 中图分类号: O648 Effects of Molecular Structure on Surfactin Micellization Activity LI Yi ZOU Ai-Hua YE Ru-Qiang MU Bo-Zhong* (Institute of Applied Chemistry, East China University of Science and Technology, Shanghai 200237) Abstract: We produced a group of surfactin isoforms using Bacillus subtilis HSO121. The micellization activity properties such as surface and interfacial tensions, micropolarity, micelle size distribution and morphology of this group of surfactin micellar solutions were investigated by surface and interfacial tension, fluorescence, dynamic light-scattering (DLS), and freeze-fracture transmission electron microscopy (FF-TEM) measurements. With an increase in the chain length, we found that the surface and interfacial activities of the surfactins increased and the surfactins tended to form larger micelle aggregates. Key Words: Surfactin; Micelle; Fluorescence; Dynamic light-scattering; Freeze-fracture transmission electron microscopy 5 1 引 言 Kakinuma 等 确定为含有7 个α-氨基酸和β-羟基脂