并以其原理成功设计与制备新型催化剂.pptVIP

One of the Holy Grails of Organic Chemistry However, within nature, a class of bacteria commonly referred to as methanotrophs, are known to mediate the reaction to convert methane to methanol efficiently under ambient conditions of temperature and pressure. An enzyme in these bacteria, the particulate methane monooxygenase (pMMO), is believed to catalyze the direct insertion of an oxygen atom into methane by using metal clusters. Sunney Chan of the Institute of Chemistry has recently proposed a new oxidation mechanism based on use of metal clusters to harness the “singlet oxene”, the most rea