《inorganic-organic》课件.pptVIP

High-Performance NanostructuredInorganic Organic Heterojunction Solar Cells Jeong Ah Chang, Jae Hui Rhee, Sang Hyuk Im, Yong Hui Lee, Hi-jung Kim, Sang Il Seok,* Md. K. Nazeeruddin,and Michael Gratzel 2010 American Chemical Society We report all solid-state nanostructured inorganic organic heterojunction solar cells fabricated by depositing Sb2S3 and poly(3-hexylthiophene) (P3HT) on the surface of a mesoporous TiO2 layer, where Sb2S3 acts as an absorbing semiconductor and P3HT acts as both a hole conductor and light absorber. These inorganic organic light harvesters perform remarkably well with a maximum incident-photon-to-current ef?ciency (IPCE) of 80% and power conversion ef?ciency of 5.13% under air-mass 1.5 global (AM 1.5G) illumination with the intensity of 100 mW cm -2 Among the several novel PV devices, dye-sensitized solar cells (DSSCs) and organic solar cells (OSCs), which exhibit ef?ciencies of 11.53 and 6.77%, respectively, are considered to represent low-cost alternatives to conventional inorganic devices. However, liquid-electrolyte-based DSSCs suffer from the problem of solvent leakage, and OSCs have a signi?cantly short lifetime. To overcome this disadvantage, solid-state organic hole-transporting materials spiro-MeO-TAD have been investigated, which gave 5% certi?ed ef?cency. Inorganic p-typematerials such as CuI and CuSCN, conducting polymers such as poly(3-hexylthiophene) (P3HT) and poly(3,4-ethylenedioxythio-phene) PEDOT, polyaniline, polydiacetyllene,and so forth have also been studied asmaterials for fabricating solid hole-transporter. we study the performances of inorganic - organic heterojunction solar cells by depositing Sb2S3 as a sensitizer onto mesoporous-TiO2 and P3HT acts as both a hole conductor and light absorber, that is, a hole-conducting dye. Crystalline Sb2S3 used as a sensitizer in this study is one of the most promising Semiconductor materials for photovoltaic cells because of its high absorption coef?cient (1.8